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In organic chemistry, a methyl group is an alkyl derived from methane, containing one carbon atom bonded to three hydrogen atoms, having chemical formula CH 3 (whereas normal methane has the formula CH 4). In formulas, the group is often abbreviated as Me. This hydrocarbon group occurs in many organic compounds. It is a very stable group in ...
A motorized miter saw. A miter saw or mitre saw is a saw used to make accurate crosscuts and miters in a workpiece by positioning a mounted blade onto a board. A miter saw in its earliest form was composed of a back saw in a miter box, but in modern implementation consists of a powered circular saw that can be positioned at a variety of angles and lowered onto a board positioned against a ...
Organotin compounds are those with tin linked to hydrocarbons. The compound on the picture is trimethyltin chloride, an example of organotin compounds.. Organotin chemistry is the scientific study of the synthesis and properties of organotin compounds or stannanes, which are organometallic compounds containing tin–carbon bonds.
A conjugated 1,4 addition using a Gilman reagent with an arbitrary R group. These reagents are useful because, unlike related Grignard reagents and organolithium reagents, they react with organic halides to replace the halide group with an R group (the Corey–House reaction). Such displacement reactions allow for the synthesis of complex ...
The earliest mitre clamps are a simple spring in a C-shape with sharpened points that are sprung onto the outside corner of the mitre joint. [citation needed]In a later design, right angled plates are higher than the screws and the holder.
TMSCl is reactive toward nucleophiles, resulting in the replacement of the chloride. In a characteristic reaction of TMSCl, the nucleophile is water, resulting in hydrolysis to give the hexamethyldisiloxane: + + The related reaction of trimethylsilyl chloride with alcohols can be exploited to produce anhydrous solutions of hydrochloric acid in alcohols, which find use in the mild synthesis of ...
Ethers are required to stabilize the organomagnesium compound. Water and air, which rapidly destroy the reagent by protonolysis or oxidation, are excluded. [1] Although the reagents still need to be dry, ultrasound can allow Grignard reagents to form in wet solvents by activating the magnesium such that it consumes the water. [2]
Tetramethylsilane is the accepted internal standard for calibrating chemical shift for 1 H, 13 C and 29 Si NMR spectroscopy in organic solvents (where TMS is soluble). In water, where it is not soluble, sodium salts of DSS, 2,2-dimethyl-2-silapentane-5-sulfonate, are used instead.
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