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The most common example of roasting is the oxidation of metal sulfide ores. The metal sulfide is heated in the presence of air to a temperature that allows the oxygen in the air to react with the sulfide to form sulfur dioxide gas and solid metal oxide. The solid product from roasting is often called "calcine".
Sorel cement (also known as magnesia cement or magnesium oxychloride) is a non-hydraulic cement first produced by the French chemist Stanislas Sorel in 1867. [1]In fact, in 1855, before working with magnesium compounds, Stanislas Sorel first developed a two-component cement by mixing zinc oxide powder with a solution of zinc chloride.
Other metal oxides can be used, such as chromium oxide, to generate the given metal in its elemental form. For example, a copper thermite reaction using copper oxide and elemental aluminum can be used for creating electric joints in a process called cadwelding, that produces elemental copper (it may react violently): 3 CuO + 2 Al → 3 Cu + Al ...
Also, DUCRETE presents environmentally friendly properties. The table below shows the effectiveness of converting depleted uranium into concrete, since potential leaching is decreased in a high order. The leach test used was the EPA Toxicity characteristic leaching procedure (TCLP), which is used to assess heavy metal risks to the environment.
The general reaction of oxide removal is: Metal oxide + Acid → Salt + Water. Salts are ionic in nature and can cause problems from metallic leaching or dendrite growth, with possible product failure. In some cases, particularly in high-reliability applications, flux residues must be removed.
The coating is a chemical conversion of the substrate metal into its oxide, and grows both inwards and outwards from the original metal surface. Because it grows inward into the substrate, it has excellent adhesion to the substrate metal. A wide range of substrate alloys can be coated, including all wrought aluminum alloys and most cast alloys ...
To attempt to simplify and to stylize a very complex set of various reactions, the whole ASR reaction, after its complete evolution (ageing process) in the presence of sufficient Ca 2+ cations available in solution, could be compared to the pozzolanic reaction which would be catalysed by the undesirable presence of excessive concentrations of alkali hydroxides (NaOH and KOH) in the concrete.
While the use of uranium metal rather than oxide made reprocessing more straightforward and therefore cheaper, the need to reprocess fuel a short time after removal from the reactor meant that the fission product hazard was severe. Expensive remote handling facilities were required to address this danger.