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Class 3: Flammable Liquids A flammable liquid is a liquid having a flash point of not more than 60 °C (140 °F), or any material in a liquid phase with a flash point at or above 37.8 °C (100 °F) that is intentionally heated and offered for transportation or transported at or above its flash point in a bulk packaging. The following exceptions ...
Prior to bringing regulations in line with the United Nations Globally Harmonized System of Classification and Labeling of Chemicals (GHS) in 2012, OSHA considered flammable liquids to be those with a flash point below 37.8 °C/100 °F. Those with flash points above 37.8 °C/100 °F and below 93.3 °C/200 °F were classified as combustible liquids.
Substances and mixtures which, in contact with water, emit flammable gases are categorized from 1 to 3 based on the ignitability of the gas emitted. Oxidizing liquids contribute to the combustion of other materials and are categorized from 1 to 3 in decreasing oxidizing potential. Oxidizing solids follow the same criteria as oxidizing liquids.
Flammable gases – Gases which at 20 °C and a standard pressure of 101.3 kPa: are ignitable when in a mixture of 13 percent or less by volume with air; or; have a flammable range with air of at least 12 percentage points regardless of the lower flammable limit. Alternative sign. Division 2.1 Non-flammable non-toxic gases – Gases which:
Extremely flammable gas H221: Flammable gas H222: Extremely flammable material H223: Flammable material H224: Extremely flammable liquid and vapour H225: Highly flammable liquid and vapour H226: Flammable liquid and vapour H227: Combustible liquid H228: Flammable solid H229: Pressurized container: may burst if heated H230
From 1996, the Recommendations were effectively split into two parts: the Model Regulations, which form a suggested drafting for laws and regulations on the transport of dangerous goods; and the Manual of Tests and Criteria, which contains technical information about methods of testing products to ascertain their hazards.
Flammable gases, or very volatile flammable liquids with flash points below 73 °F (23 °C), and boiling points below 100 °F (38 °C). Materials may ignite spontaneously with air (e.g., propane). 3. Materials capable of ignition under almost all normal temperature conditions.
Liquids having a flash point below 22.8 °C (73 °F) and having a boiling point at or above 37.8 °C (100 °F) or having a flash point between 22.8 and 37.8 °C (73 and 100 °F). 4 Will rapidly or completely vaporize at normal atmospheric pressure and temperature, or is readily dispersed in air and will burn readily (e.g., gasoline , acetylene ...
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