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The pyrite is stable until exposed to air, at which point the pyrite rapidly oxidises and produces sulfuric acid. The impacts of acid sulfate soil leachate may persist over a long time, and/or peak seasonally (after dry periods with the first rains).
In that study, a proposal for the rate at which A.ferrooxidans can oxidise pyrite is the ability to use ferrous iron to generate a ferric iron catalyst : Fe 2+ + 1 ⁄ 4 O 2 + H + → Fe 3+ + 1 ⁄ 2 H 2 O. Under the above acidic conditions, ferric iron (Fe 3+) is a more potent oxidant than oxygen, resulting in faster pyrite oxidation rates.
The chemistry of oxidation of pyrites, the production of ferrous ions and subsequently ferric ions, is very complex, and this complexity has considerably inhibited the design of effective treatment options. [6] Although a host of chemical processes contribute to acid mine drainage, pyrite oxidation is by far the greatest contributor.
The strong acidification of the medium caused by pyrite oxidation releases bicarbonate ions (HCO − 3) or carbon dioxide (CO 2) along with calcium (Ca 2+) and sulfate ions (SO 2− 4). Full pyrite oxidation can be schematized as: 2 FeS 2 + 7.5 O 2 + 4 H 2 O → Fe 2 O 3 + 4 H 2 SO 4. The sulfuric acid released by pyrite oxidation then reacts ...
Oxygen dissolves into freshwater when rainfall or river penetrates soil with organic matter. [53] Oxygen may lost under redox reactions and microbiological processes. Oxidation of pyrite or sulphide minerals also consume the dissolved oxygen inside water. [53] Dissolved oxygen concentration level in groundwater decreases during long travel ...
In ore deposit geology, supergene processes or enrichment are those that occur relatively near the surface as opposed to deep hypogene processes. Supergene processes include the predominance of meteoric water circulation (i.e. water derived from precipitation) with concomitant oxidation and chemical weathering.
Pyrite oxidation is sufficiently exothermic that underground coal mines in high-sulfur coal seams have occasionally had serious problems with spontaneous combustion. [47] The solution is the use of buffer blasting and the use of various sealing or cladding agents to hermetically seal the mined-out areas to exclude oxygen.
Diagenesis (/ ˌ d aɪ. ə ˈ dʒ ɛ n ə s ɪ s /) is the process of physical and chemical changes in sediments first caused by water-rock interactions, microbial activity, and compaction after their deposition. Increased pressure and temperature only start to play a role as sediments become buried much deeper in the Earth's crust. [1]