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  2. Variational method (quantum mechanics) - Wikipedia

    en.wikipedia.org/wiki/Variational_method...

    The ground state energy would then be 8E 1 = −109 eV, where E 1 is the Rydberg constant, and its ground state wavefunction would be the product of two wavefunctions for the ground state of hydrogen-like atoms: [2]: 262 (,) = (+) /. where a 0 is the Bohr radius and Z = 2, helium's nuclear charge.

  3. Quantum vacuum state - Wikipedia

    en.wikipedia.org/wiki/Quantum_vacuum_state

    The video of an experiment showing vacuum fluctuations (in the red ring) amplified by spontaneous parametric down-conversion.. If the quantum field theory can be accurately described through perturbation theory, then the properties of the vacuum are analogous to the properties of the ground state of a quantum mechanical harmonic oscillator, or more accurately, the ground state of a measurement ...

  4. Ground effect - Wikipedia

    en.wikipedia.org/wiki/Ground_effect

    Ground effect may refer to: Ground effect (aerodynamics), the increased lift and decreased aerodynamic drag of a wing close to a fixed surface; Ground effect (cars), an effect that creates downforce, primarily in racing cars; Ground-effect vehicle, a vehicle which attains level flight near the surface of the Earth due to ground effect

  5. Field effect (chemistry) - Wikipedia

    en.wikipedia.org/wiki/Field_effect_(chemistry)

    This cubane derivative has four linkers but the acidic proton still feels the same effect from the C-X dipole because the interaction is a field effect. [ 11 ] In the cis-11,12-dichloro-9,10-dihydro-9,10-ethano-2-anthroic acid syn and anti isomers seen below and to the left, the chlorines provide a field effect.

  6. Taft equation - Wikipedia

    en.wikipedia.org/wiki/Taft_equation

    where ⁡ is the ratio of the rate of the substituted reaction compared to the reference reaction, ρ* is the sensitivity factor for the reaction to polar effects, σ* is the polar substituent constant that describes the field and inductive effects of the substituent, δ is the sensitivity factor for the reaction to steric effects, and E s is ...

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  8. Solvatochromism - Wikipedia

    en.wikipedia.org/wiki/Solvatochromism

    The solvatochromic effect is the way the spectrum of a substance (the solute) varies when the substance is dissolved in a variety of solvents. In this context, the dielectric constant and hydrogen bonding capacity are the most important properties of the solvent.

  9. Intersystem crossing - Wikipedia

    en.wikipedia.org/wiki/Intersystem_crossing

    Fluorescence microscopy relies upon fluorescent compounds, or fluorophores, in order to image biological systems.Since fluorescence and phosphorescence are competitive methods of relaxation, a fluorophore that undergoes intersystem crossing to the triplet excited state no longer fluoresces and instead remains in the triplet excited state, which has a relatively long lifetime, before ...

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