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Graphene quantum dots (GQDs) are graphene nanoparticles with a size less than 100 nm. [1] Due to their exceptional properties such as low toxicity, stable photoluminescence , chemical stability and pronounced quantum confinement effect, GQDs are considered as a novel material for biological, opto-electronics, energy and environmental applications.
Graphene quantum dots have also been blended with organic electronic materials to improve efficiency and lower cost in photovoltaic devices and organic light emitting diodes compared to graphene sheets. These graphene quantum dots were functionalized with organic ligands that experience photoluminescence from UV–visible absorption. [103]
These silicon quantum dots can be used in numerous situations which include photochemical and biological applications such as the use of silicon layers for photovoltaic applications. [24] In an experiment using silicon quantum dots near the interface of the substrate and the quantum dots, the power conversion efficiency of the solar cell increased.
A graphene quantum dot (GQD) is a graphene fragment with a size lesser than 100 nm. The properties of GQDs are different from bulk graphene due to the quantum confinement effects which only become apparent when the size is smaller than 100 nm. [214] [215] [216]
Graphene quantum dots (GQDs) keep all dimensions less than 10 nm. Their size and edge crystallography govern their electrical, magnetic, optical, and chemical properties. GQDs can be produced via graphite nanotomy [ 85 ] or via bottom-up, solution-based routes ( Diels-Alder, cyclotrimerization and/or cyclodehydrogenation reactions ). [ 86 ]
Graphene doped with various gaseous species (both acceptors and donors) can be returned to an undoped state by gentle heating in vacuum. [22] [24] Even for dopant concentrations in excess of 10 12 cm −2 carrier mobility exhibits no observable change. [24] Graphene doped with potassium in ultra-high vacuum at low temperature can reduce ...
Molecular simulations through a coarse-grained model with parameters from semi-empirical quantum mechanics calculations can be used to prove the experimental process. Ultrathin single-crystal PbS ( lead sulfur ) sheets with micro scale in x-, y- dimensions can be obtained using a hot colloidal synthesis method. [ 11 ]
Quantum dots (QDs) are nano-scale semiconductor particles on the order of 2–10 nm in diameter. They possess electrical properties between those of bulk semi-conductors and individual molecules, as well as optical characteristics that make them suitable for applications where fluorescence is desirable, such as medical imaging.
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