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A network solid or covalent network solid (also called atomic crystalline solids or giant covalent structures) [1] [2] is a chemical compound (or element) in which the atoms are bonded by covalent bonds in a continuous network extending throughout the material.
Solids can be classified according to the nature of the bonding between their atomic or molecular components. The traditional classification distinguishes four kinds of bonding: [1] Covalent bonding, which forms network covalent solids (sometimes called simply "covalent solids") Ionic bonding, which forms ionic solids
Molecular solids can be either ductile or brittle, or a combination depending on the crystal face stressed. [5] [11] Both ductile and brittle solids undergo elastic deformation till they reach the yield stress. [8] [11] Once the yield stress is reached, ductile solids undergo a period of plastic deformation and eventually fracture. Brittle ...
Covalently bonded solids (sometimes called covalent network solids) are typically formed from one or more non-metals, such as carbon or silicon and oxygen, and are often very hard, rigid, and brittle.
At pressures higher than 110 GPa and temperatures around 2000 K, nitrogen forms a network solid, bound by covalent bonds in a cubic-gauche structure, abbreviated as cg-N. The cubic-gauche form has space group I2 1 3. Each unit cell has edge length 3.805 Å, and contains eight nitrogen atoms. [23]
In chemistry, a formula unit is the smallest unit of a non-molecular substance, such as an ionic compound, covalent network solid, or metal. [1] [2] It can also refer to the chemical formula for that unit. Those structures do not consist of discrete molecules, and so for them, the term formula unit is used.
This page was last edited on 20 July 2010, at 03:13 (UTC).; Text is available under the Creative Commons Attribution-ShareAlike 4.0 License; additional terms may ...
Metallic glasses, for example, are typically well described by the dense random packing of hard spheres, whereas covalent systems, such as silicate glasses, have sparsely packed, strongly bound, tetrahedral network structures. These very different structures result in materials with very different physical properties and applications.