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The hydrogen chromate ion may be protonated, with the formation of molecular chromic acid, H 2 CrO 4, but the pK a for the equilibrium H 2 CrO 4 ⇌ HCrO − 4 + H + is not well characterized. Reported values vary between about −0.8 and 1.6. [4] The dichromate ion is a somewhat weaker base than the chromate ion: [5]
It may be formed by the salt metathesis reaction of potassium chromate and iron(III) nitrate, which gives potassium nitrate as byproduct. 2 Fe(NO 3) 3 + 3 K 2 CrO 4 → Fe 2 (CrO 4)3 + 6 KNO 3. It also can be formed by the oxidation by air of iron and chromium oxides in a basic environment: 4 Fe 2 O 3 + 6 Cr 2 O 3 + 9 O 2 → 4 Fe 2 (CrO 4) 3
It can be represented by the chemical formula of Fe Cr 2 O 4. It is an oxide mineral belonging to the spinel group. The element magnesium can substitute for iron in variable amounts as it forms a solid solution with magnesiochromite (Mg Cr 2 O 4). [6] Substitution of the element aluminium can also occur, leading to hercynite (Fe Al 2 O 4). [7]
The structure of nickel chromate is the same as for chromium vanadate, CrVO 4. Crystals have an orthorhombic structure with unit cell sizes a = 5.482 Å, b = 8.237 Å, c = 6.147 Å. The cell volume is 277.6 Å 3 with four formula per unit cell. [5] [7] Nickel chromate is dark in colour, unlike most other chromates which are yellow. [3]
Partial predominance diagram for chromate. Molecular chromic acid, H 2 CrO 4, in principle, resembles sulfuric acid, H 2 SO 4. It would ionize accordingly: H 2 CrO 4 ⇌ [HCrO 4] − + H + The pK a for the equilibrium is not well characterized. Reported values vary between about −0.8 to 1.6. [4]
Sodium chromate (Na 2 CrO 4) Chromium(VI) compounds in solution can be detected by adding an acidic hydrogen peroxide solution. The unstable dark blue chromium(VI) peroxide (CrO 5) is formed, which can be stabilized as an ether adduct CrO 5 ·OR 2. [6] Chromic acid has the hypothetical formula H 2 CrO 4. It is a vaguely described chemical ...
Calcium chromate is an inorganic compound with the formula CaCrO 4, i.e. the chromate salt of calcium. It is a bright yellow solid which is normally found in the dihydrate form CaCrO 4 ·2H 2 O. A very rare anhydrous mineral form exists in nature, which is known as chromatite .
Caesium chromate or cesium chromate is an inorganic compound with the formula Cs 2 CrO 4. It is a yellow crystalline solid that is the caesium salt of chromic acid, and it crystallises in the orthorhombic system. Its major application in the past was for the production of caesium vapour during vacuum tube manufacture. [2]