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The simplest theory to predict the behaviour of detonations in gases is known as the Chapman–Jouguet (CJ) condition, developed around the turn of the 20th century. This theory, described by a relatively simple set of algebraic equations, models the detonation as a propagating shock wave accompanied by exothermic heat release.
In spark-ignition internal combustion engines, knocking (also knock, detonation, spark knock, pinging or pinking) occurs when combustion of some of the air/fuel mixture in the cylinder does not result from propagation of the flame front ignited by the spark plug, but when one or more pockets of air/fuel mixture explode outside the envelope of the normal combustion front.
Typical detonation velocities for organic dust mixtures range from 1400 to 1650 m/s. [2] Gas explosions can either deflagrate or detonate based on confinement; detonation velocities are generally around 1700 m/s [3] [4] [5] but can be as high as 3000 m/s. [6] Solid explosives often have detonation velocities ranging beyond 4000 m/s to 10300 m/s.
The duration of the blast wave depends on the type of explosive material and the distance from the point of detonation. The blast wave progresses from the source of explosion as a sphere of compressed and rapidly expanding gases, which displaces an equal volume of air at a very high velocity. The velocity of the blast wave in air may be ...
It states that the detonation propagates at a velocity at which the reacting gases just reach sonic velocity (in the frame of the leading shock wave) as the reaction ceases. [1] [2] David Chapman [3] and Émile Jouguet [4] originally (c. 1900) stated the condition for an infinitesimally thin detonation.
The phenomenon is exploited in pulse detonation engines, because a detonation produces a more efficient combustion of the reactants than a deflagration does, i.e. giving a higher yields. Such engines typically employ a Shchelkin spiral in the combustion chamber to facilitate the deflagration to detonation transition. [2] [3]
Its detonation velocity is around 5,180 m/s (17,000 ft/s). [12] Ammonium acetate and sodium dichromate are used to destroy small quantities of lead azide. [13] Lead azide has immediate deflagration to detonation transition (DDT), meaning that even small amounts undergo full detonation (after being hit by flame or static electricity). [citation ...
a small amount of a more powerful secondary explosive, directly in contact with the primary, and called "base" or "output" explosive, able to carry out the detonation through the casing of the detonator to the main explosive device to activate it. Explosives commonly used as primary in detonators include lead azide, lead styphnate, tetryl, and DDNP
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