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A complexometric indicator is an ionochromic dye that undergoes a definite color change in presence of specific metal ions. [1] It forms a weak complex with the ions present in the solution, which has a significantly different color from the form existing outside the complex. Complexometric indicators are also known as pM indicators. [2]
Back titration is a titration done in reverse; instead of titrating the original sample, a known excess of standard reagent is added to the solution, and the excess is titrated. A back titration is useful if the endpoint of the reverse titration is easier to identify than the endpoint of the normal titration, as with precipitation reactions
An indicator capable of producing an unambiguous color change is usually used to detect the end-point of the titration. Complexometric titrations are those reactions where a simple ion is transformed into a complex ion and the equivalence point is determined by using metal indicators or electrometrically. [1]
Cerimetry or cerimetric titration, also known as cerate oximetry, is a method of volumetric chemical analysis developed by Ion Atanasiu. It is a redox titration in which an iron(II)–1,10-phenanthroline complex color change indicates the end point. Ferroin can be reversibly discolored in its oxidized form upon titration with a Ce 4+ solution ...
Ion A. Atanasiu (25 September 1894 – 19 December 1978) was the founder of the Romanian School of Electrochemistry and the first to teach this subject in Romania. He is known as the originator of cerimetry , an analytical method based on Cerium (IV) as titration reagent .
Calconcarboxylic acid (IUPAC name 3-hydroxy-4-[(2-hydroxy-4-sulfonaphthalen-1-yl)diazenyl]naphthalene-2-carboxylic acid; commonly called Patton and Reeder's Indicator) is an azo dye that is used as an indicator for complexometric titrations of calcium with ethylenediaminetetraacetic acid (EDTA) in the presence of magnesium. [2]
Iodometry, known as iodometric titration, is a method of volumetric chemical analysis, a redox titration where the appearance or disappearance of elementary iodine indicates the end point. Note that iodometry involves indirect titration of iodine liberated by reaction with the analyte, whereas iodimetry involves direct titration using iodine as ...