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Aqueous carbon dioxide reacts with water to form carbonic acid which is very unstable and will dissociate rapidly into hydronium and bicarbonate. Therefore, in seawater, dissolved inorganic carbon is commonly referred to as the collection of bicarbonate, carbonate ions, and dissolved carbon dioxide (CO 2, H 2 CO 3, HCO − 3, CO 2− 3).
CO2SYS is a family of software programs that calculate chemical equilibria for aquatic inorganic carbon species and parameters. Their core function is to use any two of the four central inorganic carbon system parameters (pH, alkalinity, dissolved inorganic carbon, and partial pressure of carbon dioxide) to calculate various chemical properties of the system.
Example Bjerrum plot: Change in carbonate system of seawater from ocean acidification.. A Bjerrum plot (named after Niels Bjerrum), sometimes also known as a Sillén diagram (after Lars Gunnar Sillén), or a Hägg diagram (after Gunnar Hägg) [1] is a graph of the concentrations of the different species of a polyprotic acid in a solution, as a function of pH, [2] when the solution is at ...
The aquatic inorganic carbon system is composed of the various ionic, dissolved, solid, and/or gaseous forms of carbon dioxide in water. These species include dissolved carbon dioxide, carbonic acid, bicarbonate anion, carbonate anion, calcium carbonate, magnesium carbonate, and others. The relative amounts of each species in a body of water ...
The exact value of the CCD depends on the solubility of calcium carbonate which is determined by temperature, pressure and the chemical composition of the water – in particular the amount of dissolved CO 2 in the water. Calcium carbonate is more soluble at lower temperatures and at higher pressures.
It constitutes around 38,000 Pg C [18] and includes dissolved carbon dioxide (CO 2), bicarbonate (HCO − 3), carbonate (CO 2− 3), and carbonic acid (H 2 C O 3). The equilibrium between carbonic acid and carbonate determines the pH of the seawater. Carbon dioxide dissolves easily in water and its solubility is inversely related to temperature.
Carbon dioxide is less soluble in warmer water than cooler water, so hot water will exhibit a larger pCO 2 than cold water with the same concentration of carbon dioxide. p CO 2 can be used to describe the inorganic carbon system of a body of water, together with other parameters such as pH, dissolved inorganic carbon , and alkalinity .
Modern carbonated water is made by injecting pressurized carbon dioxide into water. [36] The pressure increases the solubility and allows more carbon dioxide to dissolve than would be possible under standard atmospheric pressure. When the bottle is opened, the pressure is released, allowing gas to exit the solution, forming the characteristic ...
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