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In electrochemistry, the electrochemical potential of electrons (or any other species) is the total potential, including both the (internal, nonelectrical) chemical potential and the electric potential, and is by definition constant across a device in equilibrium, whereas the chemical potential of electrons is equal to the electrochemical ...
The phrase "chemical potential" sometimes means "total chemical potential", but that is not universal. [13] In some fields, in particular electrochemistry, semiconductor physics, and solid-state physics, the term "chemical potential" means internal chemical potential, while the term electrochemical potential is used to mean total chemical ...
In this case, the chemical potential of a body is the infinitesimal amount of work needed to increase the average number of electrons by an infinitesimal amount (even though the number of electrons at any time is an integer, the average number varies continuously.): ( ,) = ( ), where F(N, T) is the free energy function of the grand canonical ...
A quasi Fermi level is a term used in quantum mechanics and especially in solid state physics for the Fermi level (chemical potential of electrons) that describes the population of electrons separately in the conduction band and valence band, when their populations are displaced from equilibrium.
The vertical axis of the band diagram represents the energy of an electron, which includes both kinetic and potential energy. The horizontal axis represents position, often not being drawn to scale. Note that the Heisenberg uncertainty principle prevents the band diagram from being drawn with a high positional resolution, since the band diagram ...
When a voltmeter is used to measure an electronic device, it does not quite measure the pure electric potential (also called Galvani potential).Instead, it measures the electrochemical potential, also called "fermi level difference", which is the total free energy difference per electron, including not only its electric potential energy but also all other forces and influences on the electron ...
The chemical potential μ is, by definition, the energy of adding an extra electron to the fluid. This energy may be decomposed into a kinetic energy T part and the potential energy − eφ part. Since the chemical potential is kept constant, Δ μ = Δ T − e Δ ϕ = 0. {\displaystyle \Delta \mu =\Delta T-e\Delta \phi =0.}
Electron capture for almost all non-noble gas atoms involves the release of energy [4] and thus is exothermic. The positive values that are listed in tables of E ea are amounts or magnitudes. It is the word "released" within the definition "energy released" that supplies the negative sign to ΔE.
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