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Isothiocyanates occur widely in nature and are of interest in food science and medical research. [1] Vegetable foods with characteristic flavors due to isothiocyanates include bok choy , broccoli , cabbage , cauliflower , kale , wasabi , horseradish , mustard , radish , Brussels sprouts , watercress , papaya seeds, nasturtiums , and capers . [ 1 ]
Sinigrin (the precursor to allyl isothiocyanate) broccoli family, brussels sprouts, black mustard. Glucotropaeolin (the precursor to benzyl isothiocyanate) Gluconasturtiin (the precursor to phenethyl isothiocyanate) Glucoraphanin (the precursor to sulforaphane) brassicas: broccoli, cauliflower, brussels sprouts, cabbages.
6-(Methylsulfinyl)hexyl isothiocyanate (6-MITC or 6-MSITC) is a compound within the isothiocyanate group of organosulfur compounds. 6-MITC is obtained from cruciferous vegetables, chiefly wasabi. Like other isothiocyanates, it is produced when the enzyme myrosinase transforms the associated glucosinolate into 6-MITC upon cell injury.
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When an animal chews the plant, the allyl isothiocyanate is released, repelling the animal. Human appreciation of the pungency is learned. [6]: 105 The compound has been shown to strongly repel fire ants (Solenopsis invicta). [7] AITC vapor is also used as an antimicrobial and shelf life extender in food packaging. [6]: 118–120
The term piquancy (/ ˈ p iː k ən s i /) is sometimes applied to foods with a lower degree of pungency [4] that are "agreeably stimulating to the palate". Examples of piquant food include mustard and curry. The primary substances responsible for pungent taste are capsaicin, piperine (in peppers) and allyl isothiocyanate (in radish, mustard ...
The isothiocyanate further decomposes into hydroxybenzyl alcohols with the release of thiocyanates. [1] [2] [3] In the presence of a nitrile-specifier protein, the less toxic 4-hydroxyphenylacetonitrile is formed from the mustard oil glycoside instead. The cabbage butterfly exploits this mechanism to avoid the toxic effects of the ...
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