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The Henderson–Hasselbalch equation relates the pH of a solution containing a mixture of the two components to the acid dissociation constant, K a of the acid, and the concentrations of the species in solution. [6] Simulated titration of an acidified solution of a weak acid (pK a = 4.7) with alkali
At half-neutralization the ratio [A −] / [HA] = 1; since log(1) = 0, the pH at half-neutralization is numerically equal to pK a. Conversely, when pH = pK a, the concentration of HA is equal to the concentration of A −. The buffer region extends over the approximate range pK a ± 2. Buffering is weak outside the range pK a ± 1.
In chemistry, acid value (AV, acid number, neutralization number or acidity) is a number used to quantify the acidity of a given chemical substance.It is the quantity of base (usually potassium hydroxide (KOH)), expressed as milligrams of KOH required to neutralize the acidic constituents in 1 gram of a sample.
= = Where K b is the base dissociation constant, K w is the water dissociation constant. 4. The pH after the equivalence point depends on the concentration of the conjugate base of the weak acid and the strong base of the titrant. However, the base of the titrant is stronger than the conjugate base of the acid. Therefore, the pH in this region ...
In chemistry, biochemistry, and pharmacology, a dissociation constant (K D) is a specific type of equilibrium constant that measures the propensity of a larger object to separate (dissociate) reversibly into smaller components, as when a complex falls apart into its component molecules, or when a salt splits up into its component ions.
The stepwise constant, K, for the formation of the same complex from ML and L is given by ML + L ⇌ ML 2; [ML 2] = K[ML][L] = Kβ 11 [M][L] 2. It follows that β 12 = Kβ 11. A cumulative constant can always be expressed as the product of stepwise constants. There is no agreed notation for stepwise constants, though a symbol such as K L
The Van 't Hoff equation relates the change in the equilibrium constant, K eq, of a chemical reaction to the change in temperature, T, given the standard enthalpy change, Δ r H ⊖, for the process. The subscript r {\displaystyle r} means "reaction" and the superscript ⊖ {\displaystyle \ominus } means "standard".
[15] k 1 is the rate constant for chemical uptake from water at the respiratory surface (L*kg −1 *d −1). [15] C WD is the chemical concentration dissolved in water (g*L −1). [15] k 2,k E,k G,k B are rate constants that represent excretion from the organism from the respiratory surface, fecal excretion, metabolic transformation, and growth ...