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bouveault-blanc-reduction. RSC ontology ID. RXNO:0000119. The Bouveault–Blanc reduction is a chemical reaction in which an ester is reduced to primary alcohols using absolute ethanol and sodium metal. [1] It was first reported by Louis Bouveault and Gustave Louis Blanc in 1903. [2][3][4] Bouveault and Blanc demonstrated the reduction of ethyl ...
Redox (/ ˈrɛdɒks / RED-oks, / ˈriːdɒks / REE-doks, reduction–oxidation[2] or oxidation–reduction[3]: 150 ) is a type of chemical reaction in which the oxidation states of the reactants change. [4] Oxidation is the loss of electrons or an increase in the oxidation state, while reduction is the gain of electrons or a decrease in the ...
A redox indicator (also called an oxidation-reduction indicator) is an indicator which undergoes a definite color change at a specific electrode potential. The requirement for fast and reversible color change means that the oxidation-reduction equilibrium for an indicator redox system needs to be established very quickly. Therefore, only a few ...
In electrochemistry, cyclic voltammetry (CV) is a type of potentiodynamic measurement. In a cyclic voltammetry experiment, the working electrode potential is ramped linearly versus time. Unlike in linear sweep voltammetry, after the set potential is reached in a CV experiment, the working electrode 's potential is ramped in the opposite ...
The Tishchenko reaction is an organic chemical reaction that involves disproportionation of an aldehyde in the presence of an alkoxide. The reaction is named after Russian organic chemist Vyacheslav Tishchenko, who discovered that aluminium alkoxides are effective catalysts for the reaction. [ 1 ][ 2 ][ 3 ] In the related Cannizzaro reaction ...
A redox gradient is a series of reduction-oxidation (redox) reactions sorted according to redox potential. [ 4 ][ 5 ] The redox ladder displays the order in which redox reactions occur based on the free energy gained from redox pairs. [ 4 ][ 5 ][ 6 ] These redox gradients form both spatially and temporally as a result of differences in ...
In electrochemistry, overpotential is the potential difference (voltage) between a half-reaction 's thermodynamically determined reduction potential and the potential at which the redox event is experimentally observed. [ 1 ] The term is directly related to a cell's voltage efficiency. In an electrolytic cell the existence of overpotential ...
Clathrate compound. A clathrate is a chemical substance consisting of a lattice that traps or contains molecules. The word clathrate is derived from the Latin clathratus (clatratus), meaning 'with bars, latticed '. [1] Most clathrate compounds are polymeric and completely envelop the guest molecule, but in modern usage clathrates also include ...