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Depending upon substitution, the UV absorption spectrum is changed to match the application. Concentrations normally range from 0.05% to 2%, with some applications up to 5%. Frequently, glass can be a better alternative to polymers when it comes to UV degradation. Most of the commonly used glass types are highly resistant to UV radiation ...
Effect of UV exposure on polypropylene rope. Polypropylene is liable to chain degradation from exposure to temperatures above 100 °C. Oxidation usually occurs at the tertiary carbon centers leading to chain breaking via reaction with oxygen. In external applications, degradation is evidenced by cracks and crazing.
Effect of UV exposure on polypropylene rope A plastic bag photodegraded into approximately 2,000 pieces, 1 to 25 mm each, after three months' exposure outdoors. Photodegradation made a plastic straw brittle.
This reduces the absorption of UV rays by the polymer matrix and hence reduces the rate of weathering. Phenolic benzotriazoles (e.g. UV-360, UV-328) and hydroxyphenyl-triazines (e.g. Bemotrizinol) are used to stabilise polycarbonates and acrylics, [25] oxanilides are used for polyamides and polyurethanes, while benzophenones are used for PVC.
Polypropylene, a common material in our everyday environment, is a very significant example of this approach. Its chemical structure where many tertiary carbons are present (bound to three carbon atoms and only one hydrogen) makes it a particularly sensitive material to ageing.
Olefin fiber is a synthetic fiber made from a polyolefin, such as polypropylene or polyethylene.It is used in wallpaper, carpeting, [1] ropes, and vehicle interiors. Olefin's advantages are its strength, colorfastness and comfort, its resistance to staining, mildew, abrasion, and sunlight, and its good bulk and cover.
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