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A colorless liquid, EBHP is a common hydroperoxide. It has been used as an O-atom donor in organic synthesis. It is chiral. Together with tert-butyl hydroperoxide and cumene hydroperoxide, ethylbenzene hydroperoxide is important commercially. [1] The compound is produced by direct reaction of ethylbenzene with oxygen, an autoxidation. [2]
Ethylbenzene is an organic compound with the formula C 6 H 5 CH 2 CH 3. It is a highly flammable, colorless liquid with an odor similar to that of gasoline . This monocyclic aromatic hydrocarbon is important in the petrochemical industry as a reaction intermediate in the production of styrene , the precursor to polystyrene , a common plastic ...
ethylbenzene is oxidized to ethylbenzene hydroperoxide, an epoxidizing agent in the propylene oxide/styrene process POSM; In the Bashkirov process, the autoxidation is conducted in the presence of boric acid, yielding an intermediate borate ester. The process is more selective with the boric acid, but the conversion to the alcohol requires ...
Hydrogen peroxide is the oxidant in the hydrogen peroxide to propylene oxide (HPPO) process, catalyzed by a titanium-doped silicalite: C 3 H 6 + H 2 O 2 → C 3 H 6 O + H 2 O; In principle, this process produces only water as a side product. In practice, some ring-opened derivatives of PO are generated. [12]
Important compounds made in this way include tert-butyl hydroperoxide, cumene hydroperoxide and ethylbenzene hydroperoxide: [7] R−H + O 2 → R−OOH. Auto-oxidation reaction is also observed with common ethers, such as diethyl ether, diisopropyl ether, tetrahydrofuran, and 1,4-dioxane. An illustrative product is diethyl ether peroxide.
Half the dogs received bedinvetmab and half the dogs received a sterile saline injection every 28 days for a total of three doses. [5] Before treatment and on various days throughout the study, owners used the Canine Brief Pain Inventory (CBPI) assessment tool to measure the severity of the dog's pain and the degree to which the pain interfered ...
Side effects in dogs and cats include hypersalivation, diarrhea, loss of appetite, and vomiting. [12] [16] Eight percent of dogs taking maropitant at doses meant to prevent motion sickness vomited right after, likely due to the local effects maropitant had on the gastrointestinal tract. Small amounts of food beforehand can prevent such post ...
The Dakin oxidation. The Dakin oxidation (or Dakin reaction) is an organic redox reaction in which an ortho- or para-hydroxylated phenyl aldehyde (2-hydroxybenzaldehyde or 4-hydroxybenzaldehyde) or ketone reacts with hydrogen peroxide (H 2 O 2) in base to form a benzenediol and a carboxylate.
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