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The addition of a material separation agent, such as benzene to an ethanol/water mixture, changes the molecular interactions and eliminates the azeotrope. Added in the liquid phase, the new component can alter the activity coefficient of various compounds in different ways thus altering a mixture's relative volatility.
The other application of the heteroazeotropic distillation is the separation of a binary system (A-B) forming a homogeneous azeotrope. In this case an entrainer or solvent is added to the mixture in order to form an heteroazeotrope with one or both of the components in order to help the separation of the original A-B mixture.
In 2005, the water supply to the city of Harbin in China with a population of almost nine million people, was cut off because of a major benzene exposure. [109] Benzene leaked into the Songhua River , which supplies drinking water to the city, after an explosion at a China National Petroleum Corporation (CNPC) factory in the city of Jilin on 13 ...
Advanced oxidation processes (AOPs), in a broad sense, are a set of chemical treatment procedures designed to remove organic (and sometimes inorganic) materials in water and wastewater by oxidation through reactions with hydroxyl radicals (·OH). [1]
Another application of the reagent in organic synthesis is in coupling reactions of alkanes. As an example tert-butanol is dimerized with Fenton's reagent and sulfuric acid to 2,5-dimethyl-2,5-hexanediol. [10] Fenton's reagent is also widely used in the field of environmental science for water purification and soil remediation. Various ...
The term stems from cumene (isopropyl benzene), the intermediate material during the process. It was invented by R. Ūdris and P. Sergeyev in 1942 (USSR), [1] and independently by Heinrich Hock in 1944. [2] [3] This process converts two relatively cheap starting materials, benzene and propylene, into two more valuable ones, phenol and acetone.
Given the large scale applications of LAB-derived detergents, a variety routes have been developed to produce linear alkylbenzenes: [3] The HF/n-paraffins process involving dehydrogenation of n-paraffins to olefins, and subsequent reaction with benzene using hydrogen fluoride as catalyst.
In commercial applications, the alkylating agents are generally alkenes, some of the largest scale reactions practiced in industry.Such alkylations are of major industrial importance, e.g. for the production of ethylbenzene, the precursor to polystyrene, from benzene and ethylene and for the production of cumene from benzene and propene in cumene process: