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The K ATRP value depends on the homo-cleavage energy of the alkyl halide and the redox potential of the Cu catalyst with different ligands. Given two alkyl halides (R 1-X and R 2-X) and two ligands (L 1 and L 2), there will be four combinations between different alkyl halides and ligands. Let K ij ATRP refer to the K ATRP value for R i-X and L ...
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ATRP involves the chain initiation of free radical polymerization by a halogenated organic species in the presence of a metal halide. The metal has a number of different oxidation states that allows it to abstract a halide from the organohalide, creating a radical that then starts free radical polymerization.
ATRP may refer to: GTRI Agricultural Technology Research Program; Atom transfer radical polymerization; Avios Travel Rewards Programme This page was last edited on ...
The expression ‘controlled radical polymerization’ is sometimes used to describe a radical polymerization that is conducted in the presence of agents that lead to e.g. atom-transfer radical polymerization (ATRP), nitroxide-(aminoxyl) mediated polymerization (NMP), or reversible-addition-fragmentation chain transfer (RAFT) polymerization.
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Copper-based reversible-deactivation radical polymerization (Cu-based RDRP) is a member of the class of reversible-deactivation radical polymerization. [1] In this system, various copper species are employed as the transition-metal catalyst for reversible activation/deactivation of the propagating chains responsible for uniform polymer chain growth.
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