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For example, the molecules nitrostyrene and phenethylamine are quite similar; the former can even be reduced into the latter. However, nitrostyrene's α-carbon atom is adjacent to the phenyl group; in phenethylamine this same carbon atom is the β-carbon atom, as phenethylamine (being an amine rather than a styrene) counts its atoms from the ...
The representative examples would be high nucleophilicities of hydroperoxide (HO 2 −) and hydrazine (N 2 H 4). [3] The effect is now well established with numerous examples and became an important concept in mechanistic chemistry and biochemistry. [4] However, the origin of the effect is still controversial without a clear winner.
For example, the 2 → 1 line is called "Lyman-alpha" (Ly-α), while the 7 → 3 line is called "Paschen-delta" (Pa-δ). Energy level diagram of electrons in hydrogen atom. There are emission lines from hydrogen that fall outside of these series, such as the 21 cm line.
Secondly, he found the charge-to-mass ratio of alpha particles to be half that of the hydrogen ion. Rutherford proposed three explanations: 1) an alpha particle is a hydrogen molecule (H 2) with a charge of 1 e; 2) an alpha particle is an atom of helium with a charge of 2 e; 3) an alpha particle is half a helium atom with a charge of 1 e.
Hydrogen-alpha, typically shortened to H-alpha or Hα, is a deep-red visible spectral line of the hydrogen atom with a wavelength of 656.28 nm in air and 656.46 nm in vacuum. It is the first spectral line in the Balmer series and is emitted when an electron falls from a hydrogen atom's third- to second-lowest energy level.
In organic chemistry, alpha-elimination refers to reactions of this type: [1] R 2 CHX → R 2 C: + HX. The reaction is employed to generate carbenes and nitrenes. The formation of dichlorocarbene from chloroform is an example. Alpha eliminations contrasts with beta eliminations, which are commonly used to generate alkenes: R 2 CHCXR' 2 → R 2 ...
Alpha hydroxy carboxylic acids, or α-hydroxy carboxylic acids (AHAs), are a group of carboxylic acids featuring a hydroxy group located one carbon atom away from the acid group. This structural aspect distinguishes them from beta hydroxy acids , where the functional groups are separated by two carbon atoms. [ 1 ]
An aldehyde differs from a ketone in that it has a hydrogen atom attached to its carbonyl group, making aldehydes easier to oxidize. Ketones do not have a hydrogen atom bonded to the carbonyl group, and are therefore more resistant to oxidation. They are oxidized only by powerful oxidizing agents which have the ability to cleave carbon–carbon ...