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Selenium tetrachloride is the inorganic compound composed with the formula SeCl 4. This compound exists as yellow to white volatile solid. This compound exists as yellow to white volatile solid. It is one of two commonly available selenium chlorides , the other example being selenium monochloride , Se 2 Cl 2 .
Structure of tellurium tetrachloride, tetrabromide and tetraiodide. The +2 oxidation state is exhibited by the dihalides, TeCl 2, TeBr 2 and TeI 2.The dihalides have not been obtained in pure form, [3]: 274 although they are known decomposition products of the tetrahalides in organic solvents, and the derived tetrahalotellurates are well-characterized:
Tellurium tetrachloride, illustrative cubane cluster. A cubane-type cluster is an arrangement of atoms in a molecular structure that forms a cube. In the idealized case, the eight vertices are symmetry equivalent and the species has O h symmetry. Such a structure is illustrated by the hydrocarbon cubane.
In a tetrahedral molecular geometry, a central atom is located at the center with four substituents that are located at the corners of a tetrahedron. The bond angles are arccos (− 1 / 3 ) = 109.4712206...° ≈ 109.5° when all four substituents are the same, as in methane ( CH 4 ) [ 1 ] [ 2 ] as well as its heavier analogues .
The original synthesis involved the redistribution reaction of selenium dioxide and selenium tetrachloride. Pure selenium oxydichloride autoionizes to a dimer: [4] SeOCl 2 ↔ (SeO) 2 Cl + 3 + Cl −. The SeOCl 2 is generally a labile Lewis acid and solutions of sulfur trioxide in SeOCl 2 likely form [SeOCl] + [SO 3 Cl] − the same way. [5]
Molecular geometry is the three-dimensional arrangement of the atoms that constitute a molecule. It includes the general shape of the molecule as well as bond lengths , bond angles , torsional angles and any other geometrical parameters that determine the position of each atom.
Selenium compounds are compounds containing the element selenium (Se). Among these compounds, selenium has various oxidation states , the most common ones being −2, +4, and +6. Selenium compounds exist in nature in the form of various minerals, such as clausthalite , guanajuatite , tiemannite , crookesite etc., and can also coexist with ...
Selenium tetrachloride, SeCl 4 This page was last edited on 19 March 2024, at 15:16 (UTC). Text is available under the Creative Commons Attribution-ShareAlike 4.0 ...