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Generalized to stochastic versions (stochastic transitivity), the study of transitivity finds applications of in decision theory, psychometrics and utility models. [19] A quasitransitive relation is another generalization; [5] it is required to be transitive only on its non-symmetric part. Such relations are used in social choice theory or ...
Marcus' formula shows a quadratic dependence of the Gibbs free energy of activation on the Gibbs free energy of reaction. It is general knowledge from the host of chemical experience that reactions usually are the faster the more negative is . In many cases even a linear free energy relation is found.
In chemistry, Le Chatelier's principle (pronounced UK: / l ə ʃ æ ˈ t ɛ l j eɪ / or US: / ˈ ʃ ɑː t əl j eɪ /) [1] is a principle used to predict the effect of a change in conditions on chemical equilibrium. [2] Other names include Chatelier's principle, Braun–Le Chatelier principle, Le Chatelier–Braun principle or the equilibrium ...
In mathematics, the Kronecker delta (named after Leopold Kronecker) is a function of two variables, usually just non-negative integers.The function is 1 if the variables are equal, and 0 otherwise: = {, =. or with use of Iverson brackets: = [=] For example, = because , whereas = because =.
The Van 't Hoff equation relates the change in the equilibrium constant, K eq, of a chemical reaction to the change in temperature, T, given the standard enthalpy change, Δ r H ⊖, for the process. The subscript r {\displaystyle r} means "reaction" and the superscript ⊖ {\displaystyle \ominus } means "standard".
Mathematically, = =, where / is the slope of the tangent to the coexistence curve at any point, is the molar change in enthalpy (latent heat, the amount of energy absorbed in the transformation), is the temperature, is the molar volume change of the phase transition, and is the molar entropy change of the phase transition. Alternatively, the ...
Transitivity (grammar), a property regarding whether a lexical item denotes a transitive object; Transitive verb, a verb which takes an object; Transitive case, a grammatical case to mark arguments of a transitive verb
The derivation of the Navier–Stokes equations as well as their application and formulation for different families of fluids, is an important exercise in fluid dynamics with applications in mechanical engineering, physics, chemistry, heat transfer, and electrical engineering.