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The examples "is greater than", "is at least as great as", and "is equal to" are transitive relations on various sets. As are the set of real numbers or the set of natural numbers: whenever x > y and y > z, then also x > z whenever x ≥ y and y ≥ z, then also x ≥ z whenever x = y and y = z, then also x = z. More examples of transitive ...
In theoretical chemistry, molecular electronic transitions take place when electrons in a molecule are excited from one energy level to a higher energy level. The energy change associated with this transition provides information on the structure of the molecule and determines many of its properties, such as colour .
An example of such a reaction is the ring closure of cyclopentane biradicals generated from the gas-phase thermal decomposition of 2,3-diazabicyclo[2.2.1]hept-2-ene. [ 20 ] [ 21 ] Transition state theory is also based on the assumption that atomic nuclei behave according to classical mechanics . [ 22 ]
Valency is related, though not identical, to subcategorization and transitivity, which count only object arguments – valency counts all arguments, including the subject. The linguistic meaning of valency derives from the definition of valency in chemistry. Like valency found in chemistry, there is the binding of specific elements.
For example, if two systems of ideal gases are in joint thermodynamic equilibrium across an immovable diathermal wall, then P 1 V 1 / N 1 = P 2 V 2 / N 2 where P i is the pressure in the ith system, V i is the volume, and N i is the amount (in moles, or simply the number of atoms) of gas.
The classic example is a person indifferent between 7 and 8 grams of sugar and indifferent between 8 and 9 grams of sugar, but who prefers 9 grams of sugar to 7. [1] Similarly, the Sorites paradox can be resolved by weakening assumed transitivity of certain relations to quasitransitivity.
When it is completely settled, so that macroscopic change is no longer detectable, it is in its own thermal equilibrium. It is not implied that it is necessarily in other kinds of internal equilibrium. For example, it is possible that a body might reach internal thermal equilibrium but not be in internal chemical equilibrium; glass is an ...
The concept of a transition state has been important in many theories of the rates at which chemical reactions occur. This started with the transition state theory (also referred to as the activated complex theory), developed independently in 1935 by Eyring, Evans and Polanyi, and introduced basic concepts in chemical kinetics that are still used today.