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Cation-exchange capacity (CEC) is a measure of how many cations can be retained on soil particle surfaces. [1] Negative charges on the surfaces of soil particles bind positively-charged atoms or molecules (cations), but allow these to exchange with other positively charged particles in the surrounding soil water. [ 2 ]
Download as PDF; Printable version; ... base saturation refers to the fraction of exchangeable cations that are base cations.
Stilbite shows a wide variation in exchangeable cations: silicon and aluminium ions occupy equivalent sites and can substitute for each other. Since silicon and aluminium have a different charge (Si 4+ and Al 3+ ) the ions occupying the sodium/calcium site have to adjust to maintain charge balance.
Laboratory tests used to diagnose a soil as dispersive focus on the cation exchange capacity of a soil sample and its cation breakdown. Soil cations are dominated by Ca 2+, Mg 2+, K +, and Na +, as well as H + in acidic soils. The exchangeable sodium percentage ( "ESP", (sodium / (total cations)) * 100 ) is a key indicator derived from these ...
Download as PDF; Printable version; ... A cation is a positively charged ion with fewer electrons than protons [2] ... exchangeable for monatomic ions, ...
An advantage of this method is that exchangeable cations can be removed by passing a chloride solution through the plate once the sample has been dried. Exchanging cations can be useful when establishing peaks for standards with variable interlayer cations. For example, nontronite has an interlayer which can contain both calcium and sodium. If ...
Exchangeable cations are present in the clay minerals interlayers and on the external basal planes of clay platelets. Cations also compensate the negative charges on the clay particle edges caused by the protolysis of silanol and aluminol groups ( pH dependent charges).
Montmorillonite is a subclass of smectite, a 2:1 phyllosilicate mineral characterized as having greater than 50% octahedral charge; its cation exchange capacity is due to isomorphous substitution of Mg for Al in the central alumina plane. The substitution of lower valence cations in such instances leaves the nearby oxygen atoms with a net ...