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Low-pressure phase diagram of pure iron. BCC is body centered cubic and FCC is face-centered cubic. Iron-carbon eutectic phase diagram, showing various forms of Fe x C y substances. Iron allotropes, showing the differences in structure. The alpha iron (α-Fe) is a body-centered cubic (BCC) and the gamma iron (γ-Fe) is a face-centered cubic (FCC).
Iron-carbon phase diagram, showing the conditions under which austenite (γ) is stable in carbon steel. Allotropes of iron; alpha iron and gamma iron. Austenite, also known as gamma-phase iron (γ-Fe), is a metallic, non-magnetic allotrope of iron or a solid solution of iron with an alloying element. [1]
Cementite (or iron carbide) is a compound of iron and carbon, more precisely an intermediate transition metal carbide with the formula Fe 3 C. By weight, it is 6.67% carbon and 93.3% iron. It has an orthorhombic crystal structure. [4]
Iron-carbon phase diagram. α-Iron is a fairly soft metal that can dissolve only a small concentration of carbon (no more than 0.021% by mass at 910 °C). [133] Austenite (γ-iron) is similarly soft and metallic but can dissolve considerably more carbon (as much as 2.04% by mass at 1146 °C).
Cooling a hypoeutectoid steel (less than 0.77 wt% C) results in a lamellar-pearlitic structure of iron carbide layers with α-ferrite (nearly pure iron) between. If it is hypereutectoid steel (more than 0.77 wt% C) then the structure is full pearlite with small grains (larger than the pearlite lamella) of cementite formed on the grain boundaries.
Pearlite occurs at the eutectoid of the iron-carbon phase diagram (near the lower left). Pearlite is a two-phased, lamellar (or layered) structure composed of alternating layers of ferrite (87.5 wt%) and cementite (12.5 wt%) that occurs in some steels and cast irons.
Martensite in AISI 4140 steel 0.35% carbon steel, water-quenched from 870 °C. Martensite is a very hard form of steel crystalline structure. It is named after German metallurgist Adolf Martens. By analogy the term can also refer to any crystal structure that is formed by diffusionless transformation. [1]
The carbon content of steel is between 0.02% and 2.14% by weight for plain carbon steel (iron-carbon alloys). Too little carbon content leaves (pure) iron quite soft, ductile, and weak. Carbon contents higher than those of steel make a brittle alloy commonly called pig iron.