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  2. Tris(pentafluorophenyl)borane - Wikipedia

    en.wikipedia.org/wiki/Tris(pentafluorophenyl)borane

    Tris(pentafluorophenyl)borane, sometimes referred to as "BCF", is the chemical compound (C 6 F 5) 3 B.It is a white, volatile solid. The molecule consists of three pentafluorophenyl groups attached in a "paddle-wheel" manner to a central boron atom; the BC 3 core is planar.

  3. Isomerization - Wikipedia

    en.wikipedia.org/wiki/Isomerization

    In chemistry, isomerization or isomerisation is the process in which a molecule, polyatomic ion or molecular fragment is transformed into an isomer with a different chemical structure. [1] Enolization is an example of isomerization, as is tautomerization .

  4. Lithium tetrakis(pentafluorophenyl)borate - Wikipedia

    en.wikipedia.org/wiki/Lithium_tetrakis(pentafluo...

    The anion is tetrahedral with B-C bond lengths of approximately 1.65 Angstroms. The salt has only been obtained as the etherate, and the crystallography confirms that four ether (OEt 2) molecules are bound to the lithium cation, with Li-O bond lengths of approximately 1.95 Å.

  5. Valence isomer - Wikipedia

    en.wikipedia.org/wiki/Valence_isomer

    Download as PDF; Printable version; ... In organic chemistry, ... Pentacyclo[5.1.0.0 2,4. 0 3,5.0 6,8]octane (octabisvalene) is the third saturated valence isomer ...

  6. Organoxenon chemistry - Wikipedia

    en.wikipedia.org/wiki/Organoxenon_chemistry

    Organoxenon chemistry is the study of the properties of organoxenon compounds, which contain carbon to xenon chemical bonds. The first organoxenon compounds were divalent, such as (C 6 F 5 ) 2 Xe. The first tetravalent organoxenon compound, [C 6 F 5 XeF 2 ][BF 4 ], was synthesized in 2004. [ 1 ]

  7. Penex - Wikipedia

    en.wikipedia.org/wiki/Penex

    In the petroleum industry, much research has been done on the upgrading of light hydrocarbons.The realisation that normal pentane is one of the most important remaining components of naphtha that can be easily upgraded prompted Phillips Petroleum to investigate the various processes for converting normal (linear) pentane into (branched) isopentane.

  8. Beckmann rearrangement - Wikipedia

    en.wikipedia.org/wiki/Beckmann_rearrangement

    In the third step, an isomerization step protonates the nitrogen atom leading to the amide. The Beckmann rearrangement mechanism The same computation with a hydroxonium ion and 6 molecules of water has the same result, but when the migrating substituent is a phenyl group, the mechanism favors the formation of an intermediate three-membered π ...

  9. Linkage isomerism - Wikipedia

    en.wikipedia.org/wiki/Linkage_isomerism

    In chemistry, linkage isomerism or ambidentate isomerism is a form of isomerism in which certain coordination compounds have the same composition but differ in their metal atom's connectivity to a ligand. Typical ligands that give rise to linkage isomers are: cyanide, CN − – isocyanide, NC −; cyanate, OCN − – isocyanate, NCO −

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