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By removing ethylene by oxidation, the permanganate delays the ripening, increasing the fruit's shelf life up to 4 weeks without the need for refrigeration. [ 52 ] [ 53 ] [ 54 ] The chemical reaction, in which ethylene (C 2 H 4 ) is oxidised by potassium permanganate (KMnO 4 ) to carbon dioxide (CO 2 ), manganese oxide (MnO 2 ) and potassium ...
The Étard reaction is a chemical reaction that involves the direct oxidation of an aromatic or heterocyclic bound methyl group to an aldehyde using chromyl chloride. [1] [2] [3] For example, toluene can be oxidized to benzaldehyde. It is named for the French chemist Alexandre Léon Étard (5 January 1852, Alençon – 1 May 1910).
Toluene (/ ˈ t ɒ l. j u iː n /), also known as toluol (/ ˈ t ɒ l. j u. ɒ l,-ɔː l,-oʊ l /), is a substituted aromatic hydrocarbon [15] with the chemical formula C 6 H 5 CH 3, often abbreviated as PhCH 3, where Ph stands for the phenyl group. It is a colorless, water-insoluble liquid with the odor associated with paint thinners.
A permanganate (/ p ər ˈ m æ ŋ ɡ ə n eɪ t, p ɜːr-/) [1] is a chemical compound with the manganate(VII) ion, MnO − 4, the conjugate base of permanganic acid. Because the manganese atom has a +7 oxidation state, the permanganate(VII) ion is a strong oxidising agent. The ion is a transition metal ion with a tetrahedral structure. [2]
The exothermic (heat producing) reaction between potassium permanganate (KMnO 4), a strong oxidizing agent, and glycerol (C 3 H 5 (OH) 3), a readily oxidised organic substance, is an example of an experiment sometimes referred to as a "chemical volcano". [7] [8]
The chemical chameleon reaction shows the process in reverse, by reducing violet potassium permanganate first to green potassium manganate and eventually to brown manganese dioxide: [1] [2] [5] KMnO 4 (violet) → K 2 MnO 4 (green) → MnO 2 (brown/yellow suspension) Blue potassium hypomanganate may also form as an intermediate. [6]
The in situ in ISCO is just Latin for "in place", signifying that ISCO is a chemical oxidation reaction that occurs at the site of the contamination. The remediation of certain organic substances such as chlorinated solvents ( trichloroethene and tetrachloroethene ), and gasoline-related compounds ( benzene , toluene , ethylbenzene , MTBE , and ...
Through a variety of mechanisms, the removal of a hydride equivalent converts a primary or secondary alcohol to an aldehyde or ketone, respectively. The oxidation of primary alcohols to carboxylic acids normally proceeds via the corresponding aldehyde, which is transformed via an aldehyde hydrate ( gem -diol, R-CH(OH) 2 ) by reaction with water.