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The mechanical equivalent of heat was a concept that had an important part in the development and acceptance of the conservation of energy and the establishment of the science of thermodynamics in the 19th century. Its independent and simultaneous discovery by James Prescott Joule and by Julius Robert von Mayer led to a priority dispute.
Joule expansion. The Joule expansion, in which a volume Vi = V0 is expanded to a volume Vf = 2V0 in a thermally isolated chamber. A free expansion of a gas can be achieved by moving the piston out faster than the fastest molecules in the gas. The Joule expansion (a subset of free expansion) is an irreversible process in thermodynamics in which ...
Joule heating (also known as resistive, resistance, or Ohmic heating) is the process by which the passage of an electric current through a conductor produces heat.. Joule's first law (also just Joule's law), also known in countries of the former USSR as the Joule–Lenz law, [1] states that the power of heating generated by an electrical conductor equals the product of its resistance and the ...
Using these values, Joule was able to determine the mechanical equivalent of heat. Joule estimated a mechanical equivalent of heat to be 819 ft•lbf/Btu (4.41 J/cal). The modern day definitions of heat, work, temperature, and energy all have connection to this experiment. In this arrangement of apparatus, it never happens that the process runs ...
Caloric theory. The caloric theory is an obsolete scientific theory that heat consists of a self-repellent fluid called caloric that flows from hotter bodies to colder bodies. Caloric was also thought of as a weightless gas that could pass in and out of pores in solids and liquids. The "caloric theory" was superseded by the mid-19th century in ...
e. The laws of thermodynamics are a set of scientific laws which define a group of physical quantities, such as temperature, energy, and entropy, that characterize thermodynamic systems in thermodynamic equilibrium. The laws also use various parameters for thermodynamic processes, such as thermodynamic work and heat, and establish relationships ...
Joule's apparatus for measuring the mechanical equivalent of heat. Most established scientists, such as William Henry, [13] as well as Thomas Thomson, believed that there was enough uncertainty in the caloric theory to allow its adaptation to account for the new results. It had certainly proved robust and adaptable up to that time.
The macroscopic energy equation for infinitesimal volume used in heat transfer analysis is [6] = +, ˙, where q is heat flux vector, −ρc p (∂T/∂t) is temporal change of internal energy (ρ is density, c p is specific heat capacity at constant pressure, T is temperature and t is time), and ˙ is the energy conversion to and from thermal ...