Search results
Results from the WOW.Com Content Network
The "size" of the charge in an ionic bond depends on the number of electrons transferred. An aluminum atom, for example, with a +3 charge has a relatively large positive charge. That positive charge then exerts an attractive force on the electron cloud of the other ion, which has accepted the electrons from the aluminum (or other) positive ion.
Well characterized examples of transition metal peroxides include the d 10 metal cations: zinc peroxide (ZnO 2), two polymorphs (both explosive) of mercury peroxide (HgO 2), and cadmium peroxide (CdO 2). Peroxide is a common ligand in metal complexes. Within the area of transition metal dioxygen complexes, O 2− 2 functions as a bidentate ...
Examples of tetrazol-5-ylidenes based on tetrazole have been prepared by Araki. [15] The N1 and N3 positions are substituted with alkyl or aryl groups. Transition metal complexes of these carbenes have been generated in situ. Mesoionic carbenes based on isoxazole and thiazole have been reported by Albrecht [16] and Bertrand [17] respectively ...
The perovskite structure of BSCCO, a high-temperature superconductor and a strongly correlated material.. Strongly correlated materials are a wide class of compounds that include insulators and electronic materials, and show unusual (often technologically useful) electronic and magnetic properties, such as metal-insulator transitions, heavy fermion behavior, half-metallicity, and spin-charge ...
Examples of nonpolar surfaces include the rocksalt (100) surface, the rutile (100), (110) and (001) surfaces and the pervoskite (100) surface. [2] An example of a polar surface is the rocksalt (111) surface. [2] In general, a polar surface is less stable than a nonpolar surface because a dipole moment increases the surface Gibbs energy.
For example, the colour of chromate, dichromate and permanganate ions is due to LMCT transitions. Another example is that mercuric iodide , HgI 2 , is red because of a LMCT transition. A metal-to-ligand charge transfer (MLCT) transition will be most likely when the metal is in a low oxidation state and the ligand is easily reduced.
For example, d-wave or triplet superconductor, or a Fulde–Ferrell–Larkin–Ovchinnikov superconductor. Ferromagnetic superconductor: Materials that display intrinsic coexistence of ferromagnetism and superconductivity. Charge-4e superconductor: A proposed state in which electrons are not bound as Cooper pairs but as quadruplets of electrons.
Ionic hydrides are used as bases and, occasionally, as reducing reagents in organic synthesis. [12] C 6 H 5 C(O)CH 3 + KH → C 6 H 5 C(O)CH 2 K + H 2. Typical solvents for such reactions are ethers. Water and other protic solvents cannot serve as a medium for ionic hydrides because the hydride ion is a stronger base than hydroxide and most ...