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The ancient Greek understanding of physics was limited to the statics of simple machines (the balance of forces), and did not include dynamics or the concept of work. During the Renaissance the dynamics of the Mechanical Powers, as the simple machines were called, began to be studied from the standpoint of how far they could lift a load, in addition to the force they could apply, leading ...
PV work is an important topic in chemical thermodynamics. For a process in a closed system, occurring slowly enough for accurate definition of the pressure on the inside of the system's wall that moves and transmits force to the surroundings, described as quasi-static, [30] [31] work is represented by the following equation between differentials:
Power is the rate with respect to time at which work is done; it is the time derivative of work: =, where P is power, W is work, and t is time.. We will now show that the mechanical power generated by a force F on a body moving at the velocity v can be expressed as the product: = =
In physical chemistry, the Arrhenius equation is a formula for the temperature dependence of reaction rates.The equation was proposed by Svante Arrhenius in 1889, based on the work of Dutch chemist Jacobus Henricus van 't Hoff who had noted in 1884 that the Van 't Hoff equation for the temperature dependence of equilibrium constants suggests such a formula for the rates of both forward and ...
Now substitute equations (a2) and (a4) into equation (a1) to obtain ... Derivation of discrete formula and work expression ... Adiabatic lapse rate;
In chemistry, the rate equation (also known as the rate law or empirical differential rate equation) is an empirical differential mathematical expression for the reaction rate of a given reaction in terms of concentrations of chemical species and constant parameters (normally rate coefficients and partial orders of reaction) only. [1]
The Archard wear equation is a simple model used to describe sliding wear and is based on the theory of asperity contact. The Archard equation was developed much later than Reye's hypothesis [] (sometimes also known as energy dissipative hypothesis), though both came to the same physical conclusions, that the volume of the removed debris due to wear is proportional to the work done by friction ...
Other work terms are added on per system requirements. [11] Each quantity in the equations above can be divided by the amount of substance, measured in moles, to form molar Gibbs free energy. The Gibbs free energy is one of the most important thermodynamic functions for the characterization of a system.