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In physics and chemistry, an equation of state is a thermodynamic equation relating state variables, which describe the state of matter under a given set of physical conditions, such as pressure, volume, temperature, or internal energy. [1] Most modern equations of state are formulated in the Helmholtz free energy.
Only one equation of state will not be sufficient to reconstitute the fundamental equation. All equations of state will be needed to fully characterize the thermodynamic system. Note that what is commonly called "the equation of state" is just the "mechanical" equation of state involving the Helmholtz potential and the volume:
joule per kilogram per kelvin (J⋅kg −1 ⋅K −1) viscous damping coefficient kilogram per second (kg/s) electric displacement field also called the electric flux density coulomb per square meter (C/m 2) density: kilogram per cubic meter (kg/m 3) diameter: meter (m) distance: meter (m) direction
The CGS unit of pressure is the barye (Ba), equal to 1 dyn·cm −2, or 0.1 Pa. Pressure is sometimes expressed in grams-force or kilograms-force per square centimetre ("g/cm 2" or "kg/cm 2") and the like without properly identifying the force units. But using the names kilogram, gram, kilogram-force, or gram-force (or their symbols) as units ...
These definitions apply to all equations of state below as well. Proposed in 1873, the van der Waals equation of state was one of the first to perform markedly better than the ideal gas law. In this equation, usually is called the attraction parameter and the repulsion parameter (or the effective molecular volume). While the equation is ...
Isotherms of an ideal gas for different temperatures. The curved lines are rectangular hyperbolae of the form y = a/x. They represent the relationship between pressure (on the vertical axis) and volume (on the horizontal axis) for an ideal gas at different temperatures: lines that are farther away from the origin (that is, lines that are nearer to the top right-hand corner of the diagram ...
In physics, there are equations in every field to relate physical quantities to each other and perform calculations. Entire handbooks of equations can only summarize most of the full subject, else are highly specialized within a certain field. Physics is derived of formulae only.
1.5 psi Pressure increase per meter of a water column [26] 10 kPa 1.5 psi Decrease in air pressure when going from Earth sea level to 1000 m elevation [citation needed] +13 kPa +1.9 psi High air pressure for human lung, measured for trumpet player making staccato high notes [48] < +16 kPa +2.3 psi