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In aqueous solutions, redox potential is a measure of the tendency of the solution to either gain or lose electrons in a reaction. A solution with a higher (more positive) reduction potential than some other molecule will have a tendency to gain electrons from this molecule (i.e. to be reduced by oxidizing this other molecule) and a solution with a lower (more negative) reduction potential ...
The second factor to be considered are the values of the concentrations taken into account in the Nernst equation. To define a formal reduction potential for a biochemical reaction, the pH value, the concentrations values and the hypotheses made on the activity coefficients must always be clearly indicated.
Variations from these ideal conditions affect measured voltage via the Nernst equation. Electrode potentials of successive elementary half-reactions cannot be directly added. However, the corresponding Gibbs free energy changes (∆G°) must satisfy ∆G° = – z FE°,
In electrochemistry, the Nernst equation is a chemical thermodynamical relationship that permits the calculation of the reduction potential of a reaction (half-cell or full cell reaction) from the standard electrode potential, absolute temperature, the number of electrons involved in the redox reaction, and activities (often approximated by concentrations) of the chemical species undergoing ...
The oxidation potential for a particular electrode is just the negative of the reduction potential. A standard cell potential can be determined by looking up the standard electrode potentials for both electrodes (sometimes called half cell potentials). The one that is smaller will be the anode and will undergo oxidation.
Siméon Denis Poisson. Poisson's equation is an elliptic partial differential equation of broad utility in theoretical physics.For example, the solution to Poisson's equation is the potential field caused by a given electric charge or mass density distribution; with the potential field known, one can then calculate the corresponding electrostatic or gravitational (force) field.
The Gibbs−Duhem equation applies to homogeneous thermodynamic systems. It does not apply to inhomogeneous systems such as small thermodynamic systems, [2] systems subject to long-range forces like electricity and gravity, [3] [4] or to fluids in porous media. [5] The equation is named after Josiah Willard Gibbs and Pierre Duhem.
The electric potential also varies with temperature, concentration and pressure. Since the oxidation potential of a half-reaction is the negative of the reduction potential in a redox reaction, it is sufficient to calculate either one of the potentials. Therefore, standard electrode potential is commonly written as standard reduction potential.