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Vanadium(II) oxide is the inorganic compound with the idealized formula VO. It is one of the several binary vanadium oxides. It adopts a distorted NaCl structure and contains weak V−V metal to metal bonds. VO is a semiconductor owing to delocalisation of electrons in the t 2g orbitals.
Metallic vanadium is rare in nature (known as native vanadium), [52] [53] having been found among fumaroles of the Colima Volcano, but vanadium compounds occur naturally in about 65 different minerals. Vanadium began to be used in the manufacture of special steels in 1896. At that time, very few deposits of vanadium ores were known.
Vanadium(IV) oxide (vanadium dioxide), VO 2; Vanadium(V) oxide (vanadium pentoxide), V 2 O 5; Various other distinct phases include: Phases with the general formula V n O 2n+1 exist between V 2 O 5 and VO 2. Examples of these phases include V 3 O 7, V 4 O 9 and V 6 O 13. [1] Phases with the general formula V n O 2n−1 exist between VO 2 and V ...
Vanadium forms oxides in the +2, +3, +4 and +5 oxidation states, forming vanadium(II) oxide (VO), vanadium(III) oxide (V 2 O 3), vanadium(IV) oxide (VO 2) and vanadium(V) oxide (V 2 O 5). Vanadium(V) oxide or vanadium pentoxide is the most common, being precursor to most alloys and compounds of vanadium, and is also a widely used industrial ...
Vanadium(IV) oxide or vanadium dioxide is an inorganic compound with the formula VO 2. It is a dark blue solid. It is a dark blue solid. Vanadium (IV) dioxide is amphoteric , dissolving in non-oxidising acids to give the blue vanadyl ion , [VO] 2+ and in alkali to give the brown [V 4 O 9 ] 2− ion, or at high pH [VO 4 ] 4− . [ 4 ]
Vanadium compounds are compounds formed by the element vanadium (V). The chemistry of vanadium is noteworthy for the accessibility of the four adjacent oxidation states 2–5, whereas the chemistry of the other group 5 elements , niobium and tantalum , are somewhat more limited to the +5 oxidation state. [ 1 ]
Vanadium(V) oxide serves the crucial purpose of catalysing the mildly exothermic oxidation of sulfur dioxide to sulfur trioxide by air in the contact process: 2 SO 2 + O 2 ⇌ 2 SO 3 The discovery of this simple reaction, for which V 2 O 5 is the most effective catalyst, allowed sulfuric acid to become the cheap commodity chemical it is today.
Vanadium(III) oxide is the inorganic compound with the formula V 2 O 3. It is a black solid prepared by reduction of V 2 O 5 with hydrogen or carbon monoxide. [3] [4] It is a basic oxide dissolving in acids to give solutions of vanadium (III) complexes. [4] V 2 O 3 has the corundum structure. [4]