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In chemistry, the rate equation (also known as the rate law or empirical differential rate equation) is an empirical differential mathematical expression for the reaction rate of a given reaction in terms of concentrations of chemical species and constant parameters (normally rate coefficients and partial orders of reaction) only. [1]
where A and B are reactants C is a product a, b, and c are stoichiometric coefficients,. the reaction rate is often found to have the form: = [] [] Here is the reaction rate constant that depends on temperature, and [A] and [B] are the molar concentrations of substances A and B in moles per unit volume of solution, assuming the reaction is taking place throughout the volume of the ...
This has the same form as an equation for a straight line: = +, where x is the reciprocal of T. So, when a reaction has a rate constant obeying the Arrhenius equation, a plot of ln k versus T −1 gives a straight line, whose slope and intercept can be used to determine E a and A respectively. This procedure is common in experimental chemical ...
In consequence, the reaction rate constant increases rapidly with temperature , as shown in the direct plot of against . (Mathematically, at very high temperatures so that E a ≪ R T {\displaystyle E_{\text{a}}\ll RT} , k {\displaystyle k} would level off and approach A {\displaystyle A} as a limit, but this case does not occur under practical ...
The Darcy-Weisbach equation was difficult to use because the friction factor was difficult to estimate. [7] In 1906, Hazen and Williams provided an empirical formula that was easy to use. The general form of the equation relates the mean velocity of water in a pipe with the geometric properties of the pipe and the slope of the energy line.
In other words, it assumes that the electrode mass transfer rate is much greater than the reaction rate, and that the reaction is dominated by the slower chemical reaction rate ". [7] [circular reference] Also, at a given electrode the Tafel equation assumes that the reverse half reaction rate is negligible compared to the forward reaction rate.
Stream power is the rate of energy dissipation against the bed and banks of a river or stream per unit downstream length. It is given by the equation: = where Ω is the stream power, ρ is the density of water (1000 kg/m 3), g is acceleration due to gravity (9.8 m/s 2), Q is discharge (m 3 /s), and S is the channel slope.
In other words, F is proportional to the logarithm of x times the slope of the straight line of its lin–log graph, plus a constant. Specifically, a straight line on a lin–log plot containing points ( F 0 , x 0 ) and ( F 1 , x 1 ) will have the function:
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