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The first breakthrough in the detection of arsenic poisoning was in 1775 when Carl Wilhelm Scheele discovered a way to change arsenic trioxide to garlic-smelling arsine gas (AsH 3), by treating it with nitric acid (HNO 3) and combining it with zinc. [3] As 2 O 3 + 6 Zn + 12 HNO 3 → 2 AsH 3 + 6 Zn(NO 3) 2 + 3 H 2 O
It is rapidly transformed into grey arsenic by light. The yellow form has a density of 1.97 g/cm 3. [23] Black arsenic is similar in structure to black phosphorus. [23] Black arsenic can also be formed by cooling vapor at around 100–220 °C and by crystallization of amorphous arsenic in the presence of mercury vapors. [26] It is glassy and ...
James Marsh (2 September 1794 – 21 June 1846) was a British chemist who invented the Marsh test for detecting arsenic.Born in Kent, he was working as a labourer in Woolwich in the late 1810s and early 1820s, before joining the Royal Artillery. [1]
Arsenic trioxide should not be mixed or administered in the same infusion with other medications. [92] In pharmaceutical compounding, arsenic trioxide was used in a 1:10 trituration with lactose (Trituratio Acidi arsenicosi 1/10). To prepare the trituration, one part arsenic trioxide is placed in a mortar, and while continuously grinding, nine ...
Arsenic forms colorless, odorless, crystalline oxides As 2 O 3 ("white arsenic") and As 2 O 5 which are hygroscopic and readily soluble in water to form acidic solutions. Arsenic(V) acid is a weak acid and the salts are called arsenates , [ 5 ] the most common arsenic contamination of groundwater , and a problem that affects many people.
The crystal structure of the skutterudite mineral was determined in 1928 by Oftedahl [7] [8] to be cubic, belonging to space group Im-3 (number 204). The unit cell can be considered to consist of eight smaller cubes made up of the Co atoms. Six of these cubes are filled with (almost) square planar rings of As, each of which is oriented parallel ...
Arsenic (III) enters the cells though aquaporins 7 and 9, which is a type of aquaglyceroporin. [26] Arsenic (V) compounds use phosphate transporters to enter cells. [26] The arsenic (V) can be converted to arsenic (III) by the enzyme purine nucleoside phosphorylase. [26]
Gray arsenic, also called grey arsenic or metallic arsenic, is the most stable allotrope of the element at room temperature, and as such is its most common form. [1] This soft, brittle allotrope of arsenic has a steel gray, metallic color, and is a good conductor. [ 2 ]