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where z is the electrical charge on the ion, I is the ionic strength, ε and b are interaction coefficients and m and c are concentrations. The summation extends over the other ions present in solution, which includes the ions produced by the background electrolyte. The first term in these expressions comes from Debye–Hückel theory.
[2] [3] [4] They were first described by physical chemist Kenneth Pitzer. [5] The parameters of the Pitzer equations are linear combinations of parameters, of a virial expansion of the excess Gibbs free energy, which characterise interactions amongst ions and solvent. The derivation is thermodynamically rigorous at a given level of expansion.
The Na + and SO 2− 4 ions are spectator ions since they remain unchanged on both sides of the equation. They simply "watch" the other ions react and does not participate in any reaction, hence the name. [1] They are present in total ionic equations to balance the charges of the ions.
4 or SO 2− 4. In simpler words, an ionic bond results from the transfer of electrons from a metal to a non-metal to obtain a full valence shell for both atoms. Clean ionic bonding — in which one atom or molecule completely transfers an electron to another — cannot exist: all ionic compounds have some degree of covalent bonding or
In ionic compounds there arise characteristic distances between ion neighbours from which the spatial extension and the ionic radius of individual ions may be derived. The most common type of ionic bonding is seen in compounds of metals and nonmetals (except noble gases , which rarely form chemical compounds).
The self-ionization of water (also autoionization of water, autoprotolysis of water, autodissociation of water, or simply dissociation of water) is an ionization reaction in pure water or in an aqueous solution, in which a water molecule, H 2 O, deprotonates (loses the nucleus of one of its hydrogen atoms) to become a hydroxide ion, OH −.
The molar ionic strength, I, of a solution is a function of the concentration of all ions present in that solution. [3]= = where one half is because we are including both cations and anions, c i is the molar concentration of ion i (M, mol/L), z i is the charge number of that ion, and the sum is taken over all ions in the solution.
Ionic potential is the ratio of the electrical charge (z) to the radius (r) of an ion. [1]= = As such, this ratio is a measure of the charge density at the surface of the ion; usually the denser the charge, the stronger the bond formed by the ion with ions of opposite charge.
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