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Iodous acid is the chemical compound with the formula HIO 2. Its salts are named iodites ; these are exceedingly unstable and have been observed but never isolated. [ 1 ] They will rapidly disproportionate to molecular iodine and iodates .
Hypoiodous acid is an inorganic compound with the chemical formula H I O. It forms when an aqueous solution of iodine is treated with mercuric or silver salts. It rapidly decomposes by disproportionation: [2] 5 HIO → HIO 3 + 2 I 2 + 2 H 2 O. Hypoiodous acid is a weak acid with a pK a of about 11. The conjugate base is hypoiodite (IO −).
Natural waters contain iodine in the form of iodide and iodate, their ratio being dependent on redox conditions and pH. Iodate is the second most abundant form in water. It is mostly associated with alkaline waters and oxidizing conditions.
Iodous acid and iodite are even less stable and exist only as a fleeting intermediate in the oxidation of iodide to iodate, if at all. [13] Iodates are by far the most important of these compounds, which can be made by oxidising alkali metal iodides with oxygen at 600 °C and high pressure, or by oxidising iodine with chlorates .
Iodites (including iodous acid) are highly unstable and have been observed [1] but never isolated. [citation needed] They will rapidly disproportionate to molecular iodine and iodates. [2] However, they have been detected as intermediates in the conversion between iodide and iodate. [3] [4]
Formula Appearance Use or occurrence Potassium iodide: KI white crystals iodine component of iodized salt Hydrogen iodide: HI colourless gas strong mineral acid Silver iodide: AgI yellow powder that darkens in light photoactive component of silver-based photographic film Thyroxine (3,5,3′,5′-tetraiodothyronine) C 15 H 11 I 4 NO 4: pale ...
Chemical formula. I 2 O Molar mass: 269.808 g/mol Related compounds ... Diiodine oxide reacts with water to form hypoiodous acid: I 2 O + H 2 O → 2 HIO. References
Iodic acid is a white water-soluble solid with the chemical formula HIO 3. Its robustness contrasts with the instability of chloric acid and bromic acid. Iodic acid features iodine in the oxidation state +5 and is one of the most stable oxo-acids of the halogens. When heated, samples dehydrate to give iodine pentoxide. On further heating, the ...