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Iodous acid is the chemical compound with the formula HIO 2. Its salts are named iodites ; these are exceedingly unstable and have been observed but never isolated. [ 1 ] They will rapidly disproportionate to molecular iodine and iodates .
Hypoiodous acid is an inorganic compound with the chemical formula H I O. It forms when an aqueous solution of iodine is treated with mercuric or silver salts. It rapidly decomposes by disproportionation: [2] 5 HIO → HIO 3 + 2 I 2 + 2 H 2 O. Hypoiodous acid is a weak acid with a pK a of about 11. The conjugate base is hypoiodite (IO −).
Iodites (including iodous acid) are highly unstable and have been observed [1] but never isolated. [citation needed] They will rapidly disproportionate to molecular iodine and iodates. [2] However, they have been detected as intermediates in the conversion between iodide and iodate. [3] [4]
Iodous acid and iodite are even less stable and exist only as a fleeting intermediate in the oxidation of iodide to iodate, if at all. [13] Iodates are by far the most important of these compounds, which can be made by oxidising alkali metal iodides with oxygen at 600 °C and high pressure, or by oxidising iodine with chlorates .
This is an accepted version of this page This is the latest accepted revision, reviewed on 4 February 2025. This article is about the chemical element. For other uses, see Iodine (disambiguation). Chemical element with atomic number 53 (I) Iodine, 53 I Iodine Pronunciation / ˈ aɪ ə d aɪ n, - d ɪ n, - d iː n / (EYE -ə-dyne, -din, -deen) Appearance lustrous metallic gray solid ...
Natural waters contain iodine in the form of iodide and iodate, their ratio being dependent on redox conditions and pH. Iodate is the second most abundant form in water. It is mostly associated with alkaline waters and oxidizing conditions. [8]
Example Bjerrum plot: Change in carbonate system of seawater from ocean acidification.. A Bjerrum plot (named after Niels Bjerrum), sometimes also known as a Sillén diagram (after Lars Gunnar Sillén), or a Hägg diagram (after Gunnar Hägg) [1] is a graph of the concentrations of the different species of a polyprotic acid in a solution, as a function of pH, [2] when the solution is at ...
Iodic acid is a white water-soluble solid with the chemical formula HIO 3. Its robustness contrasts with the instability of chloric acid and bromic acid. Iodic acid features iodine in the oxidation state +5 and is one of the most stable oxo-acids of the halogens. When heated, samples dehydrate to give iodine pentoxide. On further heating, the ...