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CO2SYS is a family of software programs that calculate chemical equilibria for aquatic inorganic carbon species and parameters. Their core function is to use any two of the four central inorganic carbon system parameters (pH, alkalinity, dissolved inorganic carbon, and partial pressure of carbon dioxide) to calculate various chemical properties of the system.
Aqueous carbon dioxide reacts with water to form carbonic acid which is very unstable and will dissociate rapidly into hydronium and bicarbonate. Therefore, in seawater, dissolved inorganic carbon is commonly referred to as the collection of bicarbonate, carbonate ions, and dissolved carbon dioxide (CO 2, H 2 CO 3, HCO − 3, CO 2− 3).
The aquatic inorganic carbon system is composed of the various ionic, dissolved, solid, and/or gaseous forms of carbon dioxide in water. These species include dissolved carbon dioxide, carbonic acid, bicarbonate anion, carbonate anion, calcium carbonate, magnesium carbonate, and others. The relative amounts of each species in a body of water ...
The exact value of the CCD depends on the solubility of calcium carbonate which is determined by temperature, pressure and the chemical composition of the water – in particular the amount of dissolved CO 2 in the water. Calcium carbonate is more soluble at lower temperatures and at higher pressures.
The carbon dioxide pressure of a sample gas or liquid equilibrates through the membrane and the glass electrode measures the resulting pH of the bicarbonate solution. Clark, galvanic, and paramagnetic electrodes measure oxygen. Severinghaus electrode measures CO 2. Sanz electrode measures pH. [2]
The mixed water sample then contains both types of heavy atoms, in a far higher degree than normal water, and is now "doubly labeled." The free interchange of hydrogens between water molecules (via normal ionization) in liquid water ensures that the pools of oxygen and hydrogen in any sample of water (including the body's pool of water) will be ...
Modern carbonated water is made by injecting pressurized carbon dioxide into water. [36] The pressure increases the solubility and allows more carbon dioxide to dissolve than would be possible under standard atmospheric pressure. When the bottle is opened, the pressure is released, allowing gas to exit the solution, forming the characteristic ...
The balance of these carbonate species (which ultimately affects the solubility of carbon dioxide), is dependent on factors such as pH, as shown in a Bjerrum plot.In seawater this is regulated by the charge balance of a number of positive (e.g. Na +, K +, Mg 2+, Ca 2+) and negative (e.g. CO 3 2− itself, Cl −, SO 4 2−, Br −) ions.