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Toluene is widely used in the paint, dye, rubber, chemical, glue, printing, and pharmaceutical industries as a solvent. [38] Nail polish, paintbrush cleaners, and stain removers may contain toluene. Manufacturing of explosives (TNT) uses it as well. Toluene is also found in cigarette smoke and car exhaust.
The simplest member, toluene (or methylbenzene), has the hydrogen atom of the benzene ring replaced by a methyl group. The chemical formula of alkylbenzenes is C n H 2n-6. [2] Safety hazards of toluene. Oftentimes, toluene is used as an organic solvent.
BHT is used as a preservative ingredient in some foods. With this usage BHT maintains freshness or prevents spoilage; it may be used to decrease the rate at which the texture, color, or flavor of food changes. [25] Some food companies have voluntarily eliminated BHT from their products or have announced that they were going to phase it out. [26]
In the petroleum refining and petrochemical industries, the initialism BTX refers to mixtures of benzene, toluene, and the three xylene isomers, all of which are aromatic hydrocarbons. The xylene isomers are distinguished by the designations ortho – (or o –), meta – (or m –), and para – (or p –) as indicated in the adjacent diagram.
o-Toluidine is absorbed through inhalation and dermal contact as well as from the gastrointestinal tract. [19] [13] [20] [21]The metabolism of o-toluidine involves many competing activating and deactivating pathways, including N-acetylation, N-oxidation, and N-hydroxylation, and ring oxidation.
Structure Dipole moment: 1.35 D: 1.61 D: 1.58 D: Hazards SDS: Main hazards: flammable, ingestion and inhalation toxicity hazard Flash point: 81 °C c.c. 86 °C 86 °C c.c. GHS pictograms: RTECS number GO6300000 GO6125000 GO6475000 Related compounds Related phenols: xylenols: Related compounds bromocresol green, cresol red
Structures of the three isomers of tolyl group. In organic chemistry, tolyl groups are functional groups related to toluene. [1] They have the general formula CH 3 C 6 H 4 −R, the change of the relative position of the methyl and the R substituent on the aromatic ring can generate three possible structural isomers 1,2 (ortho), 1,3 (meta), and 1,4 (para).
Ethyltoluenes are prepared by alkylation of toluene with ethylene: CH 3 C 6 H 5 + CH 2 =CH 2 → CH 3 C 6 H 4 CH 2 CH 3. These alkylations are catalyzed by various Lewis acids, such as aluminium trichloride. 3- and 4-Ethyltoluenes are mainly of interest as precursors to methylstyrenes: CH 3 C 6 H 4 CH 2 CH 3 → CH 3 C 6 H 4 CH=CH 2 + H 2