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A conjugate acid, within the Brønsted–Lowry acid–base theory, is a chemical compound formed when an acid gives a proton (H +) to a base—in other words, it is a base with a hydrogen ion added to it, as it loses a hydrogen ion in the reverse reaction.
It is isoelectronic with nitric acid HNO 3. The bicarbonate ion carries a negative one formal charge and is an amphiprotic species which has both acidic and basic properties. It is both the conjugate base of carbonic acid H 2 CO 3; and the conjugate acid of CO 2− 3, the carbonate ion, as shown by these equilibrium reactions: CO 2− 3 + 2 H 2 ...
The acid, HA, is a proton donor which can lose a proton to become its conjugate base, A −. The base, B, is a proton acceptor which can become its conjugate acid, HB +. Most acid–base reactions are fast, so the substances in the reaction are usually in dynamic equilibrium with each other. [8]
In chemistry, protonation (or hydronation) is the adding of a proton (or hydron, or hydrogen cation), usually denoted by H +, to an atom, molecule, or ion, forming a conjugate acid. [1] (The complementary process, when a proton is removed from a Brønsted–Lowry acid, is deprotonation.) Some examples include The protonation of water by ...
It is the conjugate base of the hydrogencarbonate (bicarbonate) [8] ion, HCO − 3, which is the conjugate base of H 2 CO 3, carbonic acid. The Lewis structure of the carbonate ion has two (long) single bonds to negative oxygen atoms, and one short double bond to a neutral oxygen atom.
Bjerrum plot of speciation for a hypothetical monoprotic acid: AH concentration as a function of the difference between pK and pH. Carbonic acid is the formal Brønsted–Lowry conjugate acid of the bicarbonate anion, stable in alkaline solution. The protonation constants have been measured to great precision, but depend on overall ionic ...
With a saturated pi-system, it has no pi-acceptor properties. With multiple electronegative elements, it is not strongly basic. The latter is consistent with the pK a ’s of carbonic acid: pK 1 = 6.77 and pK 2 = 9.93. To a single metal ion, carbonate is observed to bind in both unidentate (κ 1-) and bidentate (κ 2-) fashions. [5]
For aqueous solutions of an acid HA, the base is water; the conjugate base is A − and the conjugate acid is the hydronium ion. The Brønsted–Lowry definition applies to other solvents, such as dimethyl sulfoxide: the solvent S acts as a base, accepting a proton and forming the conjugate acid SH +.