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Polymerization of ethylene. Diverse methods are employed to manipulate the initiation, propagation, and termination rates during chain polymerization. A related issue is temperature control, also called heat management, during these reactions, which are often highly exothermic. For example, for the polymerization of ethylene, 93.6 kJ of energy ...
During polymerization, a polymer spends most of its time in increasing its chain length, or propagating. After the radical initiator is formed, it attacks a monomer (Figure 11). [ 8 ] In an ethene monomer, one electron pair is held securely between the two carbons in a sigma bond .
The polymerization is obtained with a broad molecular weight distribution due to the high viscosity and lack of good heat transfer. very high molecular weights are obtained. Gel effect. For reducing the disadvantages of bulk polymerization, the process can be carried out in a solution. This is known as solution polymerization. [2]
Chain-growth polymerization or chain-growth polymerisation is a polymerization technique where monomer molecules add onto the active site on a growing polymer chain one at a time. [1] There are a limited number of these active sites at any moment during the polymerization which gives this method its key characteristics.
In polymer chemistry, chain transfer is a polymerization reaction by which the activity of a growing polymer chain is transferred to another molecule: [1] [2] + + where • is the active center, P is the initial polymer chain, X is the end group, and R is the substituent to which the active center is transferred.
Lamellae form during crystallization from the melt. The arrow shows the direction of temperature gradient. [5] Nucleation starts with small, nanometer-sized areas, where a result of heat motions in some chains or their segments occur parallel. Those seeds can either dissociate, if thermal motion destroys the molecular order, or grow further, if ...
Solution polymerization is a method of industrial polymerization. In this procedure, a monomer is dissolved in a non-reactive solvent that contains a catalyst or initiator. The reaction results in a polymer which is also soluble in the chosen solvent. Heat released by the reaction is absorbed by the solvent, reducing the reaction rate.
Figure 4: Evolution in time of storage modulus G' and loss modulus G" during a curing reaction. A simple way to monitor the change in viscosity, and thus, the extent of the reaction, in a curing process is to measure the variation of the elastic modulus. [7] To measure the elastic modulus of a system during curing, a rheometer can be used. [7]