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Anthropogenic and natural sources of bromine. The major sources include sea spray, salt lakes, marshes, volcanos, anthropogenic sources. Sinks include exchange of brominated compounds with the stratospheric and troposphere.Bromine's chemistry is linked to other halogens such as chlorine and iodine amplify atmospheric cycling that contributes to troposphere and stratosphere ozone layer ...
The marine carbon cycle is a central to the global carbon cycle and contains both inorganic carbon (carbon not associated with a living thing, such as carbon dioxide) and organic carbon (carbon that is, or has been, incorporated into a living thing). Part of the marine carbon cycle transforms carbon between non-living and living matter.
A biogeochemical cycle, or more generally a cycle of matter, [1] is the movement and transformation of chemical elements and compounds between living organisms, the atmosphere, and the Earth's crust. Major biogeochemical cycles include the carbon cycle , the nitrogen cycle and the water cycle .
A stirred BZ reaction mixture showing changes in color over time. The discovery of the phenomenon is credited to Boris Belousov.In 1951, while trying to find the non-organic analog to the Krebs cycle, he noted that in a mix of potassium bromate, cerium(IV) sulfate, malonic acid, and citric acid in dilute sulfuric acid, the ratio of concentration of the cerium(IV) and cerium(III) ions ...
Since their discovery in the late 1980s, research on these ozone depletion events has shown the central role of bromine photochemistry. The exact sources and mechanisms that release bromine are still not fully understood, but the combination of concentrated sea salt in a condensed phase substrate appears to be a pre-requisite. [7]
The mechanism is that the highly reactive hydrogen radicals, oxygen radicals, and hydroxyl radicals react with hydrobromic acid to form less reactive bromine radicals (i.e., free bromine atoms). Bromine atoms may also react directly with other radicals to help terminate the free radical chain-reactions that characterise combustion. [63] [64]
1,1,2,2-Tetrabromoethane, or simply tetrabromoethane (TBE), is a halogenated hydrocarbon, chemical formula C 2 H 2 Br 4.Although three bromine atoms may bind to one of the carbon atoms creating 1,1,1,2-tetrabromoethane this is not thermodynamically favorable, so in practice tetrabromoethane is equal to 1,1,2,2-tetrabromoethane, where each carbon atom binds two bromine atoms.