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The distribution coefficient, log D, is the ratio of the sum of the concentrations of all forms of the compound (ionized plus un-ionized) in each of the two phases, one essentially always aqueous; as such, it depends on the pH of the aqueous phase, and log D = log P for non-ionizable compounds at any pH.
Where K d is called the distribution coefficient or the partition coefficient. Concentration of X in solvent A/concentration of X in solvent B=Kď If C 1 denotes the concentration of solute X in solvent A & C 2 denotes the concentration of solute X in solvent B; Nernst's distribution law can be expressed as C 1 /C 2 = K d. This law is only ...
The distribution constant (or partition ratio) (K D) is the equilibrium constant for the distribution of an analyte in two immiscible solvents. [1] [2] [3]In chromatography, for a particular solvent, it is equal to the ratio of its molar concentration in the stationary phase to its molar concentration in the mobile phase, also approximating the ratio of the solubility of the solvent in each phase.
Compatibility is commonly described by an element's distribution coefficient. A distribution coefficient describes how the solid and liquid phases of an element will distribute themselves in a mineral. Current studies of Earth's rare trace elements seek to quantify and examine the chemical composition of elements in the Earth's crust.
The Pareto distribution, named after the Italian civil engineer, economist, and sociologist Vilfredo Pareto, [2] is a power-law probability distribution that is used in description of social, quality control, scientific, geophysical, actuarial, and many other types of observable phenomena; the principle originally applied to describing the distribution of wealth in a society, fitting the trend ...
The gamma distribution is the maximum entropy probability distribution (both with respect to a uniform base measure and a / base measure) for a random variable X for which E[X] = αθ = α/λ is fixed and greater than zero, and E[ln X] = ψ(α) + ln θ = ψ(α) − ln λ is fixed (ψ is the digamma function). [5]
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A different distribution is defined as that of the random variable defined, for a given constant μ, by (+). This random variable has a noncentral t-distribution with noncentrality parameter μ. This distribution is important in studies of the power of Student's t-test.