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If correctly selected, it reaches terminal velocity, which can be measured by the time it takes to pass two marks on the tube. Electronic sensing can be used for opaque fluids. Knowing the terminal velocity, the size and density of the sphere, and the density of the liquid, Stokes' law can be used to calculate the viscosity of the fluid.
In the ultrashort time limit, in the order of the diffusion time a 2 /D, where a is the particle radius, the diffusion is described by the Langevin equation. At a longer time, the Langevin equation merges into the Stokes–Einstein equation. The latter is appropriate for the condition of the diluted solution, where long-range diffusion is ...
For complex systems, such as electrolytic solutions, and other drivers, such as a pressure gradient, the equation must be expanded to include additional terms for interactions. A major disadvantage of the Maxwell–Stefan theory is that the diffusion coefficients , with the exception of the diffusion of dilute gases, do not correspond to the ...
The equation of motion for Stokes flow can be obtained by linearizing the steady state Navier–Stokes equations.The inertial forces are assumed to be negligible in comparison to the viscous forces, and eliminating the inertial terms of the momentum balance in the Navier–Stokes equations reduces it to the momentum balance in the Stokes equations: [1]
In order to find the weak form of the Navier–Stokes equations, firstly, consider the momentum equation [20] + + = multiply it for a test function , defined in a suitable space , and integrate both members with respect to the domain : [20] + + = Counter-integrating by parts the diffusive and the pressure terms and by using the Gauss' theorem ...
This equation is called the mass continuity equation, or simply the continuity equation. This equation generally accompanies the Navier–Stokes equation. In the case of an incompressible fluid, Dρ / Dt = 0 (the density following the path of a fluid element is constant) and the equation reduces to:
Thermodynamic work is one of the principal kinds of process by which a thermodynamic system can interact with and transfer energy to its surroundings. This results in externally measurable macroscopic forces on the system's surroundings, which can cause mechanical work, to lift a weight, for example, [1] or cause changes in electromagnetic, [2] [3] [4] or gravitational [5] variables.
This is an approximation: the actual random force has a nonzero correlation time corresponding to the collision time of the molecules. However, the Langevin equation is used to describe the motion of a "macroscopic" particle at a much longer time scale, and in this limit the δ {\displaystyle \delta } -correlation and the Langevin equation ...