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Sodium sulfide is a chemical compound with the formula Na 2 S, or more commonly its hydrate Na 2 S·9H 2 O.Both the anhydrous and the hydrated salts in pure crystalline form are colorless solids, although technical grades of sodium sulfide are generally yellow to brick red owing to the presence of polysulfides and commonly supplied as a crystalline mass, in flake form, or as a fused solid.
[1] [2] [3] Introduced by Gilbert N. Lewis in his 1916 article The Atom and the Molecule, a Lewis structure can be drawn for any covalently bonded molecule, as well as coordination compounds. [4] Lewis structures extend the concept of the electron dot diagram by adding lines between atoms to represent shared pairs in a chemical bond.
NaPb 3, NaPb, Na 9 Pb 4, Na 5 Pb 2, and Na 15 Pb 4 are some of the known sodium-lead alloys. Sodium also forms alloys with gold (NaAu 2) and silver (NaAg 2). Group 12 metals (zinc, cadmium and mercury) are known to make alloys with sodium. NaZn 13 and NaCd 2 are alloys of zinc and cadmium. Sodium and mercury form NaHg, NaHg 4, NaHg 2, Na 3 Hg 2 ...
Sodium forms alloys with many metals, such as potassium, calcium, lead, and the group 11 and 12 elements. Sodium and potassium form KNa 2 and NaK. NaK is 40–90% potassium and it is liquid at ambient temperature. It is an excellent thermal and electrical conductor.
Structure of anhydrous sodium sulfite. Sodium sulfite can be prepared by treating a solution of sodium hydroxide with sulfur dioxide. When conducted in warm water, Na 2 SO 3 initially precipitates as a white solid. With more SO 2, the solid dissolves to give the disulfite, which crystallizes upon cooling. [2]
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In the solid state this results in the distorted metal coordination observed in the tetragonal litharge structure adopted by both PbO and SnO. The formation of these heavy metal ns 2 lone pairs which was previously attributed to intra-atomic hybridization of the metal s and p states [8] has recently been shown to have a strong anion dependence. [9]
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