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Transition state theory explains the dynamics of reactions. The theory is based on the idea that there is an equilibrium between the activated complex and reactant molecules. The theory incorporates concepts from collision theory, which states that for a reaction to occur, reacting molecules must collide with a minimum energy and correct ...
This theory was developed simultaneously in 1935 by Henry Eyring, then at Princeton University, and by Meredith Gwynne Evans and Michael Polanyi of the University of Manchester. [3] [4] [5] TST is also referred to as "activated-complex theory", "absolute-rate theory", and "theory of absolute reaction rates". [6]
Complexity theory emphasizes interactions and the accompanying feedback loops that constantly change systems. While it proposes that systems are unpredictable, they are also constrained by order-generating rules. [6]: 74 Complexity theory has been used in the fields of strategic management and organizational studies.
Contemporary usage of the term complexity specifically refers to sociologic theories of society as a complex adaptive system, however, social complexity and its emergent properties are recurring subjects throughout the historical development of social philosophy and the study of social change.
In chemical kinetics, the entropy of activation of a reaction is one of the two parameters (along with the enthalpy of activation) that are typically obtained from the temperature dependence of a reaction rate constant, when these data are analyzed using the Eyring equation of the transition state theory.
The model of hierarchical complexity (MHC) is a formal theory and a mathematical psychology framework for scoring how complex a behavior is. [4] Developed by Michael Lamport Commons and colleagues, [3] it quantifies the order of hierarchical complexity of a task based on mathematical principles of how the information is organized, [5] in terms of information science.
Marcus theory is used to describe a number of important processes in chemistry and biology, including photosynthesis, corrosion, certain types of chemiluminescence, charge separation in some types of solar cells and more. Besides the inner and outer sphere applications, Marcus theory has been extended to address heterogeneous electron transfer.
Softer theories use natural language and narratives that may be imprecise, and agents are subjects having both tangible and intangible properties. Examples of hard complexity theories include Complex Adaptive Systems (CAS) and Viability Theory, and a class of softer theory is Viable System Theory. Many of the propositional consideration made in ...