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This lists the character tables for the more common molecular point groups used in the study of molecular symmetry. These tables are based on the group-theoretical treatment of the symmetry operations present in common molecules, and are useful in molecular spectroscopy and quantum chemistry. Information regarding the use of the tables, as well ...
The irreducible complex characters of a finite group form a character table which encodes much useful information about the group G in a concise form. Each row is labelled by an irreducible character and the entries in the row are the values of that character on any representative of the respective conjugacy class of G (because characters are class functions).
For any group, its character table gives a tabulation (for the classes of the group) of the characters (the sum of the diagonal elements) of the matrices of all the irreducible representations of the group. As the number of irreducible representations equals the number of classes, the character table is square.
All of the discrete point symmetries are subgroups of certain continuous symmetries. They can be classified as products of orthogonal groups O(n) or special orthogonal groups SO(n). O(1) is a single orthogonal reflection, dihedral symmetry order 2, Dih 1. SO(1) is just the identity. Half turns, C 2, are needed to complete.
All 3N degrees of freedom have symmetry relationships consistent with the irreducible representations of the molecule's point group. [1] A linear molecule is characterized as possessing a bond angle of 180° with either a C ∞v or D ∞h symmetry point group. Each point group has a character table that represents all of the possible symmetry ...
Point groups are used to describe the symmetries of geometric figures and physical objects such as molecules. Each point group can be represented as sets of orthogonal matrices M that transform point x into point y according to y = Mx. Each element of a point group is either a rotation (determinant of M = 1), or it is a reflection or improper ...
In crystallography, a crystallographic point group is a three dimensional point group whose symmetry operations are compatible with a three dimensional crystallographic lattice. According to the crystallographic restriction it may only contain one-, two-, three-, four- and sixfold rotations or rotoinversions. This reduces the number of ...
The 27 point groups in the table plus T, T d, T h, O and O h constitute 32 crystallographic point groups. Groups with n = ∞ are called limit groups or Curie groups . There are two more limit groups, not listed in the table: K (for Kugel , German for ball, sphere), the group of all rotations in 3-dimensional space; and K h , the group of all ...