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Ammonia solution, also known as ammonia water, ammonium hydroxide, ammoniacal liquor, ammonia liquor, aqua ammonia, aqueous ammonia, or (inaccurately) ammonia, is a solution of ammonia in water. It can be denoted by the symbols NH 3 (aq). Although the name ammonium hydroxide suggests a salt with the composition [NH + 4][OH −
Ammonia is moderately basic; a 1.0 M aqueous solution has a pH of 11.6, and if a strong acid is added to such a solution until the solution is neutral (pH = 7), 99.4% of the ammonia molecules are protonated. Temperature and salinity also affect the proportion of ammonium [NH 4] +.
The ammonium ion is mildly acidic, reacting with Brønsted bases to return to the uncharged ammonia molecule: [NH 4] + + B − → HB + NH 3. Thus, the treatment of concentrated solutions of ammonium salts with a strong base gives ammonia. When ammonia is dissolved in water, a tiny amount of it converts to ammonium ions: H 2 O + NH 3 ⇌ OH − ...
Note that, in a basic solution, NaHCO 3 is less water-soluble than sodium chloride. The ammonia (NH 3) buffers the solution at a basic (high) pH; without the ammonia, a hydrochloric acid byproduct would render the solution acidic, and arrest the precipitation. Here, NH 3 along with ammoniacal brine acts as a mother liquor.
In this case, the water molecule is the conjugate acid of the basic hydroxide ion after the latter received the hydrogen ion from ammonium. On the other hand, ammonia is the conjugate base for the acidic ammonium after ammonium has donated a hydrogen ion to produce the water molecule.
This reaction is showing how ammonia changes into ammonium in water and generates a hydroxide ion. The form that the ammonia takes in the water also depends on the pH and temperature. Waters that are more basic have more ammonia compared to the amount of ammonium. [21] Ammonia is directly toxic to aquatic life while ammonium is not.
Ammonia is used in its anhydrous form (a gas) and the nitric acid is concentrated. The reaction is violent owing to its highly exothermic nature. After the solution is formed, typically at about 83% concentration, the excess water is evaporated off to leave an ammonium nitrate (AN) content of 95% to 99.9% concentration (AN melt), depending on ...
A solid with enough basic strength will absorb an electrically neutral acidic indicator and cause the acidic indicator's color to change to the color of its conjugate base. [15] When performing the gaseous acid adsorption method, nitric oxide is used. [15] The basic sites are then determined by calculating the amount of carbon dioxide that is ...