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In the Staedel–Rugheimer pyrazine synthesis (1876), 2-chloroacetophenone is reacted with ammonia to the amino ketone, then condensed and then oxidized to a pyrazine. [5] A variation is the Gutknecht pyrazine synthesis (1879) also based on this selfcondensation , but differing in the way the alpha-ketoamine is synthesised.
The phenazine complex [Ru(phen) 2 (dipyrido[3,2-a:2‘,3‘-c]phenazine)] 2+ intercalates into DNA. [3]The more complex phenazines, such as the naphthophenazines, naphthazines, and naphthotolazines, may be prepared by condensing ortho-diamines with ortho-quinones [4] or by the oxidation of an ortho-diamine in the presence of α-naphthol, and by the decomposition of ortho-anilido-(-toluidido ...
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A quinoxaline, also called a benzopyrazine, in organic chemistry, is a heterocyclic compound containing a ring complex made up of a benzene ring and a pyrazine ring. It is isomeric with other naphthyridines including quinazoline, phthalazine and cinnoline. [3] It is a colorless oil that melts just above room temperature.
In anatomy, a process (Latin: processus) is a projection or outgrowth of tissue from a larger body. [1] For instance, in a vertebra, a process may serve for muscle attachment and leverage (as in the case of the transverse and spinous processes), or to fit (forming a synovial joint), with another vertebra (as in the case of the articular processes). [2]
The Kröhnke method in this synthesis was crucial due to the failure of other cyclization techniques such as the Glaser coupling or Ullmann coupling. Figure 13. Another use of the Kröhnke pyridine synthesis was the generation of a number of 2,4,6-trisubstituted pyridines that were investigated as potential topoisomerase 1 inhibitors.
The Chichibabin pyridine synthesis (/ ˈ tʃ iː tʃ iː ˌ b eɪ b iː n /) is a method for synthesizing pyridine rings. The reaction involves the condensation reaction of aldehydes, ketones, α,β-Unsaturated carbonyl compounds, or any combination of the above, with ammonia. [1] It was reported by Aleksei Chichibabin in 1924.
The term vagina is from Latin vāgīna, meaning "sheath" or "scabbard". [1] The vagina may also be referred to as the birth canal in the context of pregnancy and childbirth. [2] [3] Although by its dictionary and anatomical definitions, the term vagina refers exclusively to the specific internal structure, it is colloquially used to refer to the vulva or to both the vagina and vulva.